We assessed the role of vegetation and hydrology in the Si cycle in the Okavango Delta. Our results show a large storage of biogenic Si (BSi) in vegetation and the sediments. The biological storage is among the highest observed so far for any ecosystem worldwide. Floodplain vegetation accumulates similar amounts of BSi in both the temporary floodplains and the permanent floodplains, with most values observed between 20 and 100 g Si m −2 . This vegetation Si, after litterfall, contributes to a large biogenic Si storage in the sediments. In temporary floodplains, sediments contain less BSi (375-1950 g Si m −2 in the top 5 cm) than in the permanent floodplains (1950-3600 g Si m −2 in the top 5 cm). BSi concentrations in the floodplain sediments decline exponentially indicating rapid dissolution. In the occasional and seasonal floodplains, unidirectional solute transfer from floodplains to the islands will remove Si from the riverine systems. Our work clearly emphasizes the crucial role of floodplains and wetlands in Si transport through tropical rivers, and the potential interference of hydrology with this role.

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The trapping of organic matter w ithin plant patches in the channels of the Okavango Delta : a matter of quality Aquatic sciences : a multidisciplinary journal for theoretical and applied limnology, fisheries science and w ater technology / Centrum voor Wiskunde en Informatica, Amsterdam. Department of Algebra, Analysis and Geometry -

Wetlands fed by rivers can be a sink for elements depending on elemental concentrations, wetland hydrology, geochemistry, vegetation and climate. In the case of the Okavango Delta, northern Botswana, the outflow discharge is a small fraction (2-5%) of the inflow. This has strong potential consequences for the Delta, as it strongly affects element cycling and storage within the Delta. We estimated the inputs, behaviour and distribution of multiple elements along a longitudinal transect within the Okavango Delta, to show potential effects of retention mechanisms of different elements. High annual element input is rather attributed to discharge than to the concentration within the water, which is generally extremely low. We observed minimal enrichment of the elements within the water pathway along the transect from inflow to outlets, implying that element output is negligible. For most elements, we observed a high correlation between storage and sediment organic matter content. The organic matter content within the sediments was higher in the vegetated sediments than in non-vegetated sediments (factor ∼ 10), and a similar trend was found for most elements. In conclusion, organic matter dominated in sediments from vegetated plots and thus plays an important role in retaining the elements within the sediments of the Delta. This finding has major implications for e.g. planning constructed wetlands for water purification or element retention especially in areas with high evapotranspiration.