10% copper-substituted (BiCUVOX/Bi 2 V 0.9 Cu 0.1 O 5.5−δ ) and 5% copper/titanium double-substituted bismuth vanadate (BiCUTIVOX/Bi 2 V 0.9 (Cu 0.05 Ti 0.05 )O 5.5−δ ) platelets were formed by molten salt synthesis (MSS) using a eutectic KCl/NaCl salt mixture. The product was phase-pure within the limits of X-ray diffraction. The size and form of the platelets could be controlled by changing the heating temperature and time. The crystallite growth rate at a synthesis temperature of 650 • C and the activation energy for grain growth were determined for BICUTIVOX, which experienced inhibited growth compared to BICUVOX. Quasi-equilibrium, multifoil shapes consisting of lobes around the perimeter of the platelets were observed and explained in the context of relative two-dimensional nucleation and edge growth rates.
10% copper substituted (BiCUVOX/Bi2V0.9Cu0.1O5.5-δ) and 5% copper/titanium 10 double-substituted bismuth vanadate (BiCUTIVOX/Bi2V0.9(Cu0.05Ti0.05)O5.5-δ) platelets were formed 11 by molten salt synthesis (MSS) using a eutectic KCl/NaCl salt mixture. The product was phase 12 pure within the limits of x-ray diffraction. The size and form of the platelets could be controlled
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.