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Physical properties such as porosity and intact dry density (IDD) are compared with strength testing in relation to the Chalk formations in the cliffs of the English Channel. Natural moisture contents are close to saturation moisture contents for chalks with intact dry densities above 1.70 Mg/m3. Below this IDD, the natural moisture contents show a much greater range and greater divergence from the saturation line. There is also an indication that certain types of chalk retain water at saturation level while others gain and lose water more readily. Strength tests (Point Load Index, Brazilian Crushing Strength and Uniaxial Compressive Strengths) show up to four times reductions in strength between dry (higher strength) and saturated (lower strength) samples. Absence of a strong correlation between density and strength is interpreted as resulting from either mineralogical differences in the samples and/or textural differences between different chalks. The variation in physical properties and strength in the different chalks forming the cliffs indicates the strong stratigraphical and sedimentological controls on mechanical performance of the material and mass in cliff failures.

Estrogenic substances discharged from wastewater treatment plants have been detected in surface sediments of receiving waters, but little is known of their vertical migration through buried sediments and their potential to contaminate subsurface waters. The vertical profiles of estrogenic chemicals were investigated in sediment cores at an alluvial freshwater site (Ditchling) and a clay-rich estuarine site (Lewes), both of which are downstream of wastewater discharges into the River Ouse (Sussex, U.K.). Estrone (E1) was the predominant estrogen detected in surface and buried sediments at both sites and was detected in undisturbed clay sediments > 120 years old. Profiles of E1 at Ditchling were characterized by a prominent subsurface peak of E1 at the alluvium/clay interface (-15 cm) at a concentration (28.8 +/- 6.0 ng/g of dry wt) that was 9-fold higher than in the surface sediment. In contrast, a steady downcore decline in E1 concentrations was observed in the clay-rich Lewes core. This work provides the first in situ evidence of estrogen migration through river bed sediments and reveals that movement of estrogens through unconsolidated sediment can result in penetration to the underlying substrata and therefore the potential for groundwater contamination.