This research aims to study the effect of activated carbon particles in adsorption of the methylene blue as a replacement of wastewater treatment when coated on a high density polyethylene (HDPE) substrate (e.g. flat sheet and cosmo ball substrates). Prior to coating, the activated carbon has been cleaned using tab water to remove ashes which blocks the activated carbon pores. Coating was done by applying epoxy material using brushing technique, and then sprayed the activated carbon on epoxy either manually or using spray machine. The thickness and morphological of the coatings were characterized using Scanning Electron Microscopy (SEM). Analyses conducted have confirmed that granuler activated carbon coating layers ranged between 100 to 500 μm have been successfully deposited on different shapes of HDPE substrates. The coatings deposited on HDPE substrate produced high surface roughness of around 7 μm. The ability of the coated samples in removing the colour of methylene blue is believed due to the high porosity of the activated carbon(AC). The surface area has been increased dramatically if compared with uncoated substrate since the BET of activated carbon is 426 m2/g .

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Constructed wetlands attracted the attention of researchers as a sustainable, economic, and efficient wastewater treatment technique. Many papers showed the efficient performance of constructed wetlands to treat municipal, industrial, livestock, petroleum, and other types of wastewater, effectively removing organic matters, phosphate, nitrogen, and contaminants of emerging concern such as pharmaceuticals and antibiotics. There have been numerous reviews in the literature that studied nitrogen removal in constructed wetlands from different perspectives. However, the majority are concerned about the conventional nitrification process. It is worth mentioning that some biological nitrogen pathways other than the conventional nitrification process were implemented in constructed wetlands efficiently such as partial nitrification and denitrification, simultaneous nitrification and denitrification, anaerobic ammonium oxidation, and completely autotrophic nitrogen removal over nitrite which have been reviewed in this study. The outcomes of this study showed that anaerobic ammonium oxidation is the most common pathway applied in constructed wetlands. Moreover, this review showed that the efficient performance of these novel pathways is constrained by the difficulty of controlling the operating parameters such as dissolved oxygen, temperature, and pH.

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