This research includes preparing of some carbazole derivatives .The (3,6-Disulfonylchloride-9H-carbazole (1) was achieved by the reaction of carbazole with chloro sulfonic acid in cold condition, reaction of compound (1) with sodium azide in acetone as a solvent to give (3,6-Disulfonyl azide-9H-carbazole) (2), then reaction of compound (2) with different phosphine and phosphate compounds(1mole and 2 mole) yielded the (3,6-Disulfonyl -6-azide-3-(phosphine or phosphate imine)-9H-carbazole) derivatives (3-8) and (3,6-Disulfonyl (phosphine or phosphate imine)-