In this research, local citrus fruits, namely Garut citrus, were analyzed for electrical properties related to physicochemical properties. Electrical measurement on fruit was done by using low alternating current with a frequency varying from 50 Hz to 1 MHz. The fruits are placed between two plate electrodes and treated as dielectric material. Electrical parameters per unit of weight were used in this study to compensate variations in weight. Electrical impedance, resistance, and reactance per weight of citrus fruits will decrease if the frequency is increased. Electrical circuit models have been constructed to describe the internal conditions of citrus fruits. To indicate the fruit maturity, the physicochemical properties were used, i.e., firmness, total soluble solids, pH, and hydrogen ion concentration. The value of resistance, impedance, and reactance per weight declined during citrus fruits maturation. The correlations between electrical and physicochemical properties are investigated too. The highest consistency of correlations happens at a frequency of 1 MHz. Based on the model of an electrical circuit, the highest value of electrical resistance is outer shell and the lowest is seed. And then, the highest value of electrical capacitance is albedo and the lowest is segment. Resistance values of the parts of citrus fruits, i.e., seed, segment, segment wall, and outer shell, were decreased during maturation. While capacitance value of segment, albedo, and flavedo were increased.
The effect of chemical activators on the properties of activated carbon from sago waste was conducted in this study by using ZnCl2, H3PO4, KOH, and KMnO4 chemical solutions. The carbonized sago waste was added to each chemical solution, boiled at 85 °C for 4 h, and heated at 600 °C for 3 h. The porosity, microstructural, proximate, and surface chemistry analyses were carried out using nitrogen adsorption with employing the Brunauer Emmett Teller (BET) method and the Barret-Joyner-Halenda (BJH) calculation, scanning electron microscopy by using energy dispersive spectroscopy, X-ray diffractometer, simultaneous thermogravimetric analysis system, and the Fourier-transform infrared spectroscopy. The results showed that the activated carbon prepared using ZnCl2 acid had the highest specific surface area of 546.61 m2/g, while the KOH activating agent surpassed other chemicals in terms of a refined structure and morphology, with the lowest ash content of 10.90%. The surface chemistry study revealed that ZnCl2 and KOH activated carbon showed phenol and carboxylate groups. Hence, ZnCl2 acid was suggested as activating agents for micropore carbon, while KOH was favorable to producing a mesopore-activated carbon from sago waste.
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