Dual-fuel (DF) engines, in which premixed natural gas and air in an open-type combustion chamber is ignited by diesel-fuel pilot sprays, have been more popular for marine use than pre-chamber spark ignition (PCSI) engines because of their superior durability. However, control of ignition and combustion in DF engines is more difficult than in PCSI engines. In this context, this study focuses on the ignition stability of n-heptane pilot-fuel jets injected into a compressed premixed charge of natural gas and air at low-load conditions. To aid understanding of the experimental data, chemical-kinetics simulations were carried out in a simplified engine-environment that provided insight into the chemical effects of methane (CH4) on pilot-fuel ignition. The simulations reveal that CH4 has an effect on both stages of n-heptane autoignition: the small, first-stage, cool-flame-type, low-temperature ignition (LTI) and the larger, second-stage, high-temperature ignition (HTI). As the ratio of pilot-fuel to CH4 entrained into the spray decreases, the initial oxidization of CH4 consumes the OH radicals produced by pilot-fuel decomposition during LTI, thereby inhibiting its progression to HTI. Using imaging diagnostics, the spatial and temporal progression of LTI and HTI in DF combustion are measured in a heavy-duty optical engine, and the imaging data are analyzed to understand the cause of severe fluctuations in ignition timing and combustion completeness at low-load conditions. Images of cool-flame and hydroxyl radical (OH*) chemiluminescence serve as indicators of LTI and HTI, respectively. The cycle-to-cycle and spatial variation in ignition extracted from the imaging data are used as key metrics of comparison. The imaging data indicate that the local concentration of the pilot-fuel and the richness of the surrounding natural-gas air mixture are important for LTI and HTI, but in different ways. In particular, higher injection pressures and shorter injection durations increase the mixing rate, leading to lower concentrations of pilot-fuel more quickly, which can inhibit HTI even as LTI remains relatively robust. Decreasing the injection pressure from 80 MPa to 40 MPa and increasing the injection duration from 500 µs to 760 µs maintained constant pilot-fuel mass, while promoting robust transition from LTI to HTI by effectively slowing the mixing rate. This allows enough residence time for the OH radicals, produced by the two-stage ignition chemistry of the pilot-fuel, to accelerate the transition from LTI to HTI before being consumed by CH4 oxidation. Thus from a practical perspective, for a premixed natural gas fuel–air equivalence-ratio, it is possible to improve the “stability” of the combustion process by solely manipulating the pilot-fuel injection parameters while maintaining constant mass of injected pilot-fuel. This allows for tailoring mixing trajectories to offset changes in fuel ignition chemistry, so as to promote a robust transition from LTI to HTI by changing the balance between the local concentration of the pilot-fuel and richness of the premixed natural gas and air. This could prove to be a valuable tool for combustion design to improve fuel efficiency or reduce noise or perhaps even reduce heat-transfer losses by locating early combustion away from in-cylinder walls.

Considerable amount in 400,000 ~ 600,000 tons per year of waste vegetable oil in Japan is still flushed down the drain. Utilization of waste vegetable oil for diesel fuel leads to two advantages for environmental protection, to reduce CO 2 emission from engines and to avoid water pollution of rivers. In this study, combustion characteristics of waste vegetable oil methyl ester (WME) are in detail investigated by not only engine test run but also observation of burning flames in a visual engine. In order to reduce NOx emission of WME, emulsified waste rapeseed oil methyl ester (EME) also is tested. Engine test run shows that smoke emission from WME is lower than gas oil, that thermal efficiency of WME is the same as gas oil, and that NOx from WME is about 13 % higher than gas oil at full load. Though CO and HC emissions from WME are higher than from gas oil, absolute values of them are acceptable. According to the results, it is concluded that WME can be used for diesel engines instead of gas oil.

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SUMMARY Superconducting Transition edge sensor (TES) coupled with a heavy metal absorber is a promising microcalorimeter for Gammaray (γ-ray) spectroscopy with ultra-high energy resolution and high detection efficiency. It is very useful for the non-destructed inspection of the nuclide materials. High resolving power of γ-ray peaks can precisely identify multiple nuclides such as Plutonium (Pu) and Actinides with high efficiency and safety. For this purpose, we have developed the TES coupled with a tin absorber. We suggest the new device structure using the gold bump post which connects a tin absorber to the thermometer of the superconducting Ir/Au bilayer. High thermal conductivity of the gold bump post realized strong thermal coupling between the thermometer and the γ-ray absorber, and it brought the benefit of large pulse height and fast decay time. Our TES achieved the good energy resolution of 84 eV FWHM at 59.5 keV. Using this TES device, we also succeeded to demonstrate the nuclear material measurements. In the measurement of a Pu sample, we detected the sharp γ-ray peaks from 239 Pu and 240 Pu, and of a Fission Products (FP) sample, we observed fluorescence X-ray peaks emitted by the elements contained in FP. The TES could resolve the fine structures of each fluorescence X-ray line like K α1 and K α2 . In addition to that, we developed the TES coupled with tantalum absorber, which is expected to have higher absorption efficiency for γ-rays. This device reported the best energy resolution of 465 eV at 662 keV.