A chiral Schiff base platinum(II) complex 1 bearing polyethylene glycol (PEG) chains was synthesized. The complex was found to melt at 44 °C whereas its non‐substituted analogue 2 has a high melting point (>300 °C). Upon cooling after melting, the complex remained liquid at room temperature over 30 minutes and exhibited yellow phosphorescence. Circularly polarized phosphorescence (CPP) properties were examined and it was found that the absolute value of the luminescence dissymmetry factor (glum) increases significantly in the liquid state compared to the dilute solution state. Herein, we report the first example of CPP from solvent‐free supercooled liquids.