This study examined the adsorption of a synthetic cutting fluid and cutting fluid effluent on chitosan and SDS-modified chitosan. Chitosan and SDS-modified chitosan were prepared in form of beads and fibers. A series of batch experiments were carried out as a function of the initial concentration of cutting fluid, contact time and pH of the fluid. The contact angle study suggested that the SDS-modified chitosan was more hydrophobic than chitosan. The Zeta potential study showed that chitosan, SDS-modified chitosan and synthetic cutting fluid had a point of zero charge (PZC) at pH 7.8, 9 and 3.2, respectively. SDS-modified chitosan has a greater adsorption capacity than chitosan. The experimental results show that adsorption capacity of the cutting fluid on 1.0 g of SDS-modified chitosan at pH 3 and for a contact time of 120 min was approximately 2,500 g/kg. The adsorption capacity of chitosan and SDS-modified chitosan increased with decreasing pH. The Langmuir, Freundlich, and Brunauer Emmett and Teller (BET) adsorption models were used to explain the adsorption isotherm. The Langmuir isotherm fitted well with the experimental data of chitosan while the BET isotherm fitted well with the SDS-modified chitosan data. Pseudo first-and second-order kinetic models and intraparticle diffusion model were used to examine the kinetic data. The experimental data was fitted well to a pseudo second-order kinetic model. The significant uptake of cutting fluid on chitosan and SDS-modified chitosan were demonstrated by FT-IR spectroscopy, SEM and heat of combustion.

Industrial cutting fluid wastewater (CFW) is considered as hazardous substance due to its detrimental effects to the environment and workers welfare. Treatment of this type of wastewater was sometimes disregarded due to lack of knowledge and resources. However, adsorption, a straightforward approach, was used in this study to address this problem. The feasibility of the bagasse and modified bagasse in the adsorption of CFW was determined. Varying the adsorbent dosage resulted in an increase in the percent adsorption, whereas a decline for the adsorption capacity at equilibrium using a single-stage batch laboratory- and pilot-scale adsorption. The point of zero charge of the bagasse and the modified bagasse was measured to be at pH 5.5 and 2.4, respectively. The experiment also determined that, for a liter of CFW, 10.2 g and 59.2 g of the modified bagasse are required under laboratory- and pilot-scale systems, respectively. Isotherms of Langmuir, Freundlich, and Temkin were used in order to describe the adsorption process. It was determined that the surface heterogeneity and the pore size contributed to the adsorption of CFW; thus, Freundlich isotherm best fitted the data. Functional groups were verified using FTIR analysis and the heat of combustion, and their proximate analyses were determined. Based on the results under laboratory- and pilot-scale systems, modified bagasse is a viable material for the adsorption of CFW and solid fuel source.

Hydrogen peroxide is a strong oxidizing agent containing a peroxide functional group that easily decomposes. In this research, a commercial grade of 35 % w/w hydrogen peroxide was evaluated for thermal hazard and reactivity by differential scanning calorimetry (DSC). It was found that the calculated activation energy was 70.03 kJ/mol. The risk assessment of thermal hazard evaluated in terms of the adiabatic decomposition temperature rise at heating rate 2, 4 and 8 °C/min, were 236.5, 159.2 and 217.5 K, respectively. While the time-to-maximum rate were 79.1, 52.6 and 28.3 second, respectively. Therefore, the storage, transportation and usage, proper care must be highly careful by trained and qualified person or the chemist knowledgeable personnel.

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This research work aimed to apply the aluminium dross, waste of ADC12 and 6063 aluminium smelter grade as the raw materials produced plant fertilizer by acid treatment process with phosphoric and hydrochloric acid. Chemical properties have been tested as a chemical composition, pH, amount of macronutriants and heavy metals. The germination index testing was confirmed by using water extraction of the dross before and after pretreatment which effected on cantonese green lettuce seed. The results showed that more than 50% by weight of dross composition was alumina mainly. Others components were included oxides of silicon, magnesium, sodium, potassium, calcium, iron, and zinc. Interestingly, there are not appeared of harmful heavy metal elements. For fertilization properties, mainly nutrients as nitrogen (N), phosphorus (P), and potassium (K) were investigated. Also, the germination test was investigated in an organic fertilizer standard test method as germination index (GI). Normally, the result was found that GI of un-treated dross was lower than that of a control sample. The treated dross with HCl and phosphoric acid presented higher GI than that of a reference sample. It was concluded that both grades of dross can be used as a fertilizer with acid treatment.