Membrane distillation
(MD) uses a microporous hydrophobic membrane
to separate dissolved molecules from a liquid stream. Notwithstanding
the great potential, membrane distillation is not applied on an industrial
level yet, because of the lack of specifically developed membranes,
modules, and techno-economic data at full scale. This review gives
a comprehensive overview of the optimal membrane properties and can
serve as a guideline for the development of new membranes, specifically
for membrane distillation. Optimization of the membrane is needed
to sufficiently resist wetting. Generally, a pore diameter of 0.3
μm is recommended to balance between a high liquid entry pressure
and flux. Since vacuum membrane distillation is more sensitive to
wetting, a smaller pore diameter could be appropriate for this configuration
to avoid membrane wetting. An optimal membrane thickness is found
between 10 and 700 μm, depending on process conditions, balancing
between mass transport and energy loss. To improve the mass transfer
and energy efficiency, membrane porosity should preferably be as high
as possible (>75%), while low tortuosity (1.1–1.2) and thermal
conductivity (>0.06 w·m–1·K–1) are recommended as well.
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