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Abstract:The reactions of organic azides 40: 54:6 mixture of 8 , l l . and C,, in quan-stable towards thcrmolysis, 8 decomposed with [60]fullerene have paved the way for titative yield. No interconversion between to C,, (35 % yield) on refluxing in the synthesis of' adducts with a variety of 8 and 11 was observed. Whereas 11 was chlorobenzene for 24 h, but it did not prostructures. Treatment of [60]fullerene with duce any 11. This indicates that 9 a is an intermediate in the formation of 8 and 11. 2,2-dibenzyl-1,3-diazidopropane (10) in refluxing chlorobenzene afforded three A general mechanism for the addition of products, namely, 8, 9, and 11 in 18, 25, azides to C,, is proposed. A similar mechand 11 % yields, respectively. Thermolysis anistic pathway is suggested for the therof 9 a in refluxing chlorobenzene gave a molysis of 9 a .

The reactions of C60 with C 2 chiral 1,4-tert-alkoxy-2,3-bisazidobutanes give the corresponding chiral bisazafulleroids 2. The enantiomeric pairs of chiral bisazafulleroids 2 exhibit mirror image CD curves.

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