Developing
a fundamental understanding of how polymers respond
during hypervelocity impact (HVI), a high strain rate process, is
crucial for the potential use of polymers in HVI protection systems.
Here, we present the high-strain-rate impact behavior of commercially
available polycarbonates with two different molecular weights, 42
and 21 kg/mol. A powder gun and a two-stage light-gas gun were used
to achieve the velocities (v0) of a 4 mm projectile impacting
the polycarbonate targets over the range of 400–6,500 m/s.
The deformation behavior of the polymer during the impact event was
captured using high-speed cameras. The impact caused a variety of
responses, ranging from deflection of the projectile to complete perforation
for higher v0, leading to major debris cloud formation.
These debris clouds consist of both fluid- and dust-like ejecta. The
fluid-like debris cloud indicates the melting of polymer caused by
the conversion of kinetic energy to thermal energy and subsequent
adiabatic heating. The dust-like response can likely be attributed
to the brittle failure behavior of polymers, as the polymer became
brittle at a high strain rate. Dynamic mechanical analysis (DMA) and
dielectric thermal analysis (DETA) on the polycarbonate samples used
here indicate an approximately 40 °C increase of T
g with increasing frequency from 1 Hz to 106 Hz, and such an increase has likely led to brittle behavior. While
the leading-edge velocity of the debris clouds and perforation diameters
scale linearly with v0, we found negligible differences
in the HVI response for the two molecular weights of polycarbonate
tested here. This study displays the importance of v0 and
thickness contributing to responses of polycarbonates undergoing HVI.
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