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This paper is a part of a natural dye solar cell project. Conductive transparent oxide (CTO) films have been deposited onto preheated glass substrates using a spray pyrolysis technique. The optical, electrical, structural properties as well as thermal annealing and gamma radiation response were studied. The average optical energy gap of doped films for direct allowed and direct forbidden transitions were found to be 3.92 and 3.68 eV, respectively. The plasmon frequency and plasmon energy after doping were found to be 3.48 × 1014 s −1 and 0.23 eV. The negative absorbance of the doped film was observed in UV-Vis range after applying both thermal annealing and γ-dose irradiation with 22 kGy. The negative refractive index of the doped film in UV range (220 – 300 nm) is promising for optical applications. The electron mobility μe reached a maximum of 27.4 cm2 V−1 s−1 for Sb concentration of 10 %. The corresponding resistivity ρ, and sheet resistance Rs reached their minimum values of 1.1 × 10−3 Ω cm and 35 Ω sq−1, respectively. The dopant concentration has been increased from 4.13 × 1019 to 2.1 × 1020cm−3. The doped film was found to exhibit three diffraction peaks associated with (2 2 2), (2 0 0), and (2 1 1) reflection planes, of which the peak of (2 2 2) of Sb2O3 and the peak of (2 0 0) were very close.

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This work reports a study of corrosion lifetime of transparent electrodes deposited on the microscopic glass substrate. A procedure was developed for obtaining the transparent electrode by spray method. The corrosion lifetime variation in the presence of 1.5 M NaOH medium chemically degraded at room temperature before and after gamma irradiation was determined by measuring the evolution of the structure, electrical and optical characteristics. The mean values of transmittance up to 25 month before and after irradiation were calculated 91% ±6% and 96±7%, respectively. The average value of resistivity after corrosion and age time after γ-irradiation was 0.016±9% Ω.cm and 0.017± 4% at 1.0 kHz. No significant changes observed for 27 hr corrosion and 25 month age time of the transparent electrodes in NaOH solution.