A comparative study of near-maximum-light optical spectra of 24 Type Ia supernovae (SNe Ia) is presented. The spectra are quantified in two ways, and assigned to four groups. Seven "core-normal" SNe Ia have very similar spectra, except for strong high-velocity Ca II absorption in SN 2001el. Seven SNe Ia are assigned to a "broad-line" group, the most extreme of which is SN 1984A. Five SNe Ia, including SN 1991bg, are assigned to a "cool" group. Five SNe Ia, including SN 1991T, are assigned to a "shallow-silicon" group. Comparisons with Synow synthetic spectra provide a basis for discussion of line identifications, and an internally consistent quantification of the maximum-light spectroscopic diversity among SNe Ia. The extent to which SN Ia maximum-light spectra appear to have a continuous distribution of properties, rather than consisting of discrete subtypes, is discussed.

A comparative study of optical spectra of Type Ia supernovae (SNe Ia) is extended, in the light of new data. The discussion is framed in terms of the four groups defined in previous papers of this series: core normal (CN); broad line (BL); cool (CL); and shallow silicon (SS). Emerging features of the SN Ia spectroscopic diversity include evidence (1) that extreme CL SN 1991bg-likes are not a physically distinct subgroup and (2) for the existence of a substantial number of SN 1999aa-like SSs that are very similar to each other and distinguishable from CN even as late as three weeks after maximum light. SN 1999aa-likes may be relatively numerous, yet not a physically distinct subgroup. The efficacy of quantitative spectroscopic subclassification of SNe Ia based on the equivalent widths of absorption features near 5750Å and 6100Å near maximum light is discussed. The absolute magnitude dispersion of a small sample of CNs is no larger than the characteristic absolute magnitude uncertainty.