The preparation of new esters of o-coumaric and cinnamic acids is described. Spray applications of o-coumaric acid were inactive in vivo against Venturia inaequalis on immature leaves but alkyl esters of the acid penetrated intact leaves more readily and reduced the incidence of disease. Isobutyl o-coumarate was the most active compound. In contrast to o-coumaric acid, cinnamic acid gave some measure of control but esters of this acid were not consistently better. The most satisfactory formulation mixture for these materials contained acetone, Tween 80 and Triton X-100, giving a fine crystalline suspension.Systemic action of isobutyl o-coumarate in shoots of the apple variety Cox's Orange Pippin was demonstrated, and its presence in the upper epidermis of the first five leaves above those to which it had been applied was shown by thin-layer chromatography of extracted material.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.