The magnetization process and the magnetic domains of the FeNi (100 nm)/Cu
(2.5 nm)/FeNi (100 nm)/Cu (480 nm)/FeNi (100 nm)/Cu (2.5 nm)/FeNi (100 nm) structure were
studied. This geometry consists of two FeNi/Cu/FeNi trilayers with a thick in the direction
perpendicular to the plane of the sensitive element and narrow in the direction of the
flowing current Cu electrode in the centre. Ferromagnet/conductor/ferromagnet is the
typical geometry of magnetoimpedance thin-film-based sensitive elements used to detect
small magnetic fields. Multilayered structures were prepared by rf-sputtering in a magnetic
field of 100 Oe applied perpendicular to the Cu electrode in order to induce transverse
magnetic anisotropy. The magnetic measurements and magnetic domain structure
observations were made in magnetic fields applied one at a time parallel or perpendicular
to the Cu electrode. Different magnetization processes with non-homogeneous rotations in
the first case and dominant multiple nucleation and merging of domains in the second one
were observed.
Arrays of Fe-Co alloy nanowires with diameter around 35 nm and several micrometers in length have been synthesized by codepositing Fe and Co into porous anodic alumina. The morphology, structure, and magnetic properties of the nanowires (hysteresis loops and remanence curves) were characterized by SEM, TEM, X-ray diffraction (XRD), and VSM, respectively. The XRD patterns indicate that the Fe-Co nanowires present a body-centered cubic (bcc) structure and a preferred (110) orientation perpendicular to the template surface. From the hysteresis loops obtained with the magnetic field applied in the axis direction of the nanowires, we can observe that the coercive field slightly decreases when the nanowire length increases. This magnetic behaviour is analyzed considering the shape anisotropy and the dipolar interactions among nanowires.
The state-selective dissociation dynamics for anionic and excited neutral fragments of gaseous SiCl 4 following Cl 2p and Si 2p core-level excitations were characterized by combining measurements of the photoninduced anionic dissociation, x-ray absorption and UV/visible dispersed fluorescence. The transitions of core electrons to high Rydberg states/doubly excited states in the vicinity of both Si 2p and Cl 2p ionization thresholds of gaseous SiCl 4 lead to a remarkably enhanced production of anionic, Si − and Cl − , fragments and excited neutral atomic, Si * , fragments. This enhancement via core-level excitation near the ionization threshold of gaseous SiCl 4 is explained in terms of the contributions from the Auger decay of doubly excited states, shake-modified resonant Auger decay, or/and post-collision interaction. These complementary results provide insight into the state-selective anionic and excited neutral fragmentation of gaseous molecules via core-level excitation.
Magnetic nanoparticles have been largely proposed as means of technological tools due to its value in different fields, especially in biomedicine. Herein, we present a robust, highly reproducible and low-cost method to obtain superparamagnetic magnetite nanoparticles (MNP-II) of about 15±5 nm diameter by thermal decomposition of [Fe(acac)3] in a one-pot, two-step method. In the first step, magnetite nanoparticles (MNP-I) of lower size, 9±4 nm, with a saturation magnetization (MS) of 65 emu/g and a coercive field (Hc) of 1 Oe are obtained. In the second step, those particles MNP-I act as seeds for the final MNP-II which present a saturation magnetization of 70 emu/g and a coercive field of 12 Oe.
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