International audienceIn this paper, we produce nanoholes on a silicon surface by laser ablation. Those nanoholes lead to a yield enhancement of light-matter interaction. Performing Raman spectroscopy on silicon, an enhancement of its main Raman mode is observed: it is twice higher with the nanoholes compared to a flat surface. Such a feature appears whatever the excitation wavelength (488, 514.5 and 632.8 nm) and the laser power, revealing a broad band light-matter interaction enhancement. In addition, no change in the position and shape of the main Raman mode of silicon is observed, suggesting that no structural damages are induced by laser ablation. These results clearly demonstrate the potentiality of such nanostructures for the further development of silicon photonics. (C) 2013 Elsevier B. V. All rights reserved
International audienceWe have investigated femtosecond-laser-induced microstructures (on the surface and within the bulk), gratings, and craters in four different polymers: polymethyl methacrylate, polydimethylsiloxane, polystyrene, and polyvinyl alcohol. The structures were achieved using a Ti:sapphire laser delivering 100-fs pulses at 800 nm with a repetition rate of 1 kHz and a maximum pulse energy of 1 mJ. Local chemical modifications leading to the formation of optical centers and peroxide radicals were studied using ultraviolet-visible absorption and emission, confocal micro-Raman and electron spin resonance spectroscopic techniques. Potential applications of these structures in microfluidics, waveguides, and memory-based devices are demonstrated. (C) 2012 Society of Photo-Optical Instrumentation Engineers (SPIE). [DOI: 10.1117/1.OE.51.7.073402
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