Hot gas giant exoplanets can lose part of their atmosphere due to strong stellar irradiation, affecting their physical and chemical evolution. Studies of atmospheric escape from

Ultra-hot Jupiters are emerging as a new class of exoplanets. Studying their chemical compositions and temperature structures will improve the understanding of their mass loss rate as well as their formation and evolution. We present the detection of ionized calcium in the two hottest giant exoplanets -KELT-9b and WASP-33b. By utilizing transit datasets from CARMENES and HARPS-N observations, we achieved high confidence level detections of Ca ii using the cross-correlation method. We further obtain the transmission spectra around the individual lines of the Ca ii H&K doublet and the near-infrared triplet, and measure their line profiles. The Ca ii H&K lines have an average line depth of 2.02 ± 0.17 % (effective radius of 1.56 R p ) for WASP-33b and an average line depth of 0.78 ± 0.04 % (effective radius of 1.47 R p ) for KELT-9b, which indicates that the absorptions are from very high upper atmosphere layers close to the planetary Roche lobes. The observed Ca ii lines are significantly deeper than the predicted values from the hydrostatic models. Such a discrepancy is probably a result of hydrodynamic outflow that transports a significant amount of Ca ii into the upper atmosphere. The prominent Ca ii detection with the lack of significant Ca i detection implies that calcium is mostly ionized in the upper atmospheres of the two planets.

Aims. We explore the capabilities of CARMENES for characterizing hot-Jupiter atmospheres by targeting multiple water bands, in particular, those at 1.15 and 1.4 µm. Hubble Space Telescope observations suggest that this wavelength region is relevant for distinguishing between hazy/cloudy and clear atmospheres. Methods. We observed one transit of the hot Jupiter HD 189733 b with CARMENES. Telluric and stellar absorption lines were removed using Sysrem, which performs a principal component analysis including proper error propagation. The residual spectra were analysed for water absorption with cross-correlation techniques using synthetic atmospheric absorption models. Results. We report a cross-correlation peak at a signal-to-noise ratio (SNR) of 6.6, revealing the presence of water in the transmission spectrum of HD 189733 b. The absorption signal appeared slightly blueshifted at -3.9 ± 1.3 km s −1 . We measured the individual crosscorrelation signals of the water bands at 1.15 and 1.4 µm, finding cross-correlation peaks at SNRs of 4.9 and 4.4, respectively. The 1.4 µm feature is consistent with that observed with the Hubble Space Telescope. Conclusions. The water bands studied in this work have been mainly observed in a handful of planets from space. The ability of also detecting them individually from the ground at higher spectral resolution can provide insightful information to constrain the properties of exoplanet atmospheres. Although the current multiband detections can not yet constrain atmospheric haze models for HD 189733 b, future observations at higher signal-to-noise ratio could provide an alternative way to achieve this aim.