Structures of hard-sphere fluids from a modified fundamental-measure theory J. Chem. Phys. 117, 10156 (2002) This work is devoted to the exact statistical mechanics treatment of simple inhomogeneous few-body systems. The system of two hard spheres ͑HSs͒ confined in a hard spherical pore is systematically analyzed in terms of its dimensionality D. The canonical partition function and the one-and two-body distribution functions are analytically evaluated and a scheme of iterative construction of the D + 1 system properties is presented. We analyze in detail both the effect of high confinement, when particles become caged, and the low density limit. Other confinement situations are also studied analytically and several relations between the two HSs in a spherical pore, two sticked HSs in a spherical pore, and two HSs on a spherical surface partition functions are traced. These relations make meaningful the limiting caging and low density behavior. Turning to the system of two HSs in a spherical pore, we also analytically evaluate the pressure tensor. The thermodynamic properties of the system are discussed. To accomplish this statement we purposely focus in the overall characteristics of the inhomogeneous fluid system, instead of concentrate in the peculiarities of a few-body system. Hence, we analyze the equation of state, the pressure at the wall, and the fluid-substrate surface tension. The consequences of new results about the spherically confined system of two HSs in D dimension on the confined many HS system are investigated. New constant coefficients involved in the low density limit properties of the open and closed systems of many HS in a spherical pore are obtained for arbitrary D. The complementary system of many HS which surrounds a HS ͑a cavity inside of a bulk HS system͒ is also discussed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.