In the present study, the influence of the electrochemical potential on the tribocorrosion behavior of X20Cr13 in 0.15 molar NaCl-solution was investigated with the aid of a universal-tribometer under potentiostatic control. The resulting material loss was determined through laser confocal microscopy, while the morphology of the wear tracks and the deformation of the material structure near the surface were observed using light and scanning electron microscopy. The results showed a clear dependence of the material loss and the wear mechanisms from the applied potential. Within the cathodic region, a small amount of the material degradation could be attributed to a strong adhesion and resulting strain hardening as a consequence of an electrochemical weakening and mechanical destruction of the passive layer. The maximum of wear during polarization at the free corrosion potential under friction was explained by galvanic coupling between the wear track and the passive surface near the stability threshold between Fe2+-Ion and Fe2O3 development. Through increasing Polarization onto the free corrosion potential in the absence of friction and into the passive region, a decrease in material loss could be observed which is presumably attributed to the stable passive layer that inhibits electrochemical degradation and favors the formation of a grain refinement zone that slows down mechanical destruction.