BaFe12−xGaxO19 hexaferrites were synthesized via the usual ceramic technology; with an increase in x, the unit cell and magnetic parameters monotonically decrease.
The article reports about electric field-induced alignment of the carbon nanoparticles embedded in epoxy matrix. Optical microscopy was performed to consider the effect of the electric field magnitude and configuration, filler morphology, and aspect ratio on alignment process. Characteristic time of aligned network formation was compared with modeling predictions. Carbon nanotube and graphite nanoplatelet rotation time was estimated using an analytical model based on effective medium approach. Different depolarization factor was applied according to the geometries of the particle and electric field.Solid nanocomposites were fabricated by using AC electric field. We have investigated concentration dependence of electrical conductivity of graphite nanoplatelets/epoxy composites using two-probe technique. It was established that the electrical properties of composites with random and aligned filler distribution are differ by conductivity value at certain filler content and distinguish by a form of concentration dependence of conductivity for fillers with different morphology. These differences were explained in terms of the dynamic percolation and formation of various conductive networks: chained in case of graphite nanoplatelets and crossed framework in case of carbon nanotubes filler.
Synergistic effect causes significant decreasing of the percolation threshold in the ternary polymer composites filled with carbon nanotubes (CNT) and graphite nanoplatelets (GNP) in comparison with binary ones. Enhancement of the percolation threshold strongly depends only on the relative aspect ratios of the filler particles due to the formation of the bridges between puddles of the different filler components. Conditions of both appearance and fading away of the synergistic effect are investigated depending on the relative morphology of CNT or GNP components of the filler. Different lateral sizes, aspect ratios, and volume concentrations of both CNT and GNP in the selected ternary composites were considered. Conditions of the effective substitution of GNP with CNT and vice versa in equal volume concentrations without enlarging of the percolation threshold were established. The results are obtained numerically using the Monte Carlo simulation of the percolation threshold of the different ternary composites.
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