By electron beam evaporation, noble metals (Au, Co, Pt, and Ag) with 2 and 4 nm nominal thicknesses were coated onto multi-walled carbon nanotube layers. The metals were in the form of nanoparticles mounted onto the side walls of carbon nanotubes (CNTs) to create a metal/CNT junction.
The CNTs were directly grown on patterned Pt-electrode alumina substrates through chemical vapor deposition to produce a resistivity-based ammonia gas sensor. The metallic surface-modified CNT-based sensors were found sensitive to NH3 gas at room temperature. Compared with pristine
CNT sensor, the response of Au/CNTs sensor increased slightly, whereas the responses of the Pt/CNTs, Co/CNTs, and Ag/CNTs increased by two, three, and more than four times, respectively.
Complex ferroelectric PbTiO3-modified 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 materials were synthesized by a conventional solid-state reaction method. The addition of PbTiO3 into host 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 materials are modified the ferroelectric properties of host materials where the maximum polarization slightly increased from 23.09 C\cm2 to 23.28 C\cm2 and the remnant polarization is found to increase from 10.07 C\cm2 to 11.31 C\cm2. The large piezoelectric dynamic coefficient value of 662 pm\V is obtained for 7 mol. % PbTiO3 modified 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 compounds as solid solution. Our work is expected to contribute to the role of A-site modification in lead-free ferroelectric BaTiO3-based materials for advanced function materials for electronic device applications.
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