Summary Sun is an inexhaustible source of energy capable of fulfilling all the energy needs of humankind. The energy from the sun can be converted into electricity or used directly. Electricity can be generated from solar energy either directly using photovoltaic (PV) cells or indirectly using concentrated solar power (CSP) technology. Progress has been made to raise the efficiency of the PV solar cells that can now reach up to approximately 34.1% in multi‐junction PV cells. Electricity generation from concentrated solar technologies has a promising future as well, especially the CSP, because of its high capacity, efficiency, and energy storage capability. Solar energy also has direct application in agriculture primarily for water treatment and irrigation. Solar energy is being used to power the vehicles and for domestic purposes such as space heating and cooking. The most exciting possibility for solar energy is satellite power station that will be transmitting electrical energy from the solar panels in space to Earth via microwave beams. Solar energy has a bright future because of the technological advancement in this field and its environment‐friendly nature. The biggest challenge however facing the solar energy future is its unavailability all‐round the year, coupled with its high capital cost and scarcity of the materials for PV cells. These challenges can be met by developing an efficient energy storage system and developing cheap, efficient, and abundant PV solar cells. This article discusses the solar energy system as a whole and provides a comprehensive review on the direct and the indirect ways to produce electricity from solar energy and the direct uses of solar energy. The state‐of‐the‐art procedures being employed for PV characterization and performance rating have been summarized. Moreover, the technical, economic, environmental, and storage‐related challenges are discussed with possible solutions. Furthermore, a comprehensive list of future potential research directions in the field of direct and indirect electricity generation from solar energy is proposed.
Quartz crystal microbalance with dissipation (QCM-D) was applied to investigate the adsorption characteristics of polyacrylamide-based polymers (PAMs) on anisotropic basal planes of kaolinite. Kaolinite basal planes were differentiated by depositing kaolinite nanoparticles (KNPs) on silica and alumina sensors in solutions of controlled pH values. Adsorption of an in-house synthesized organic-inorganic Al(OH)3-PAM (Al-PAM) as an example of cationic hybrid PAM and a commercially available partially hydrolyzed polyacrylamide (MF1011) as an example of anionic PAM was studied. Cationic Al-PAM was found to adsorb irreversibly and preferentially on tetrahedral silica basal planes of kaolinite. In contrast, anionic MF1011 adsorbed strongly on aluminum-hydroxy basal planes, while its adsorption on tetrahedral silica basal planes was weak and reversible. Adsorption study revealed that both electrostatic attraction and hydrogen-bonding mechanisms contribute to adsorption of PAMs on kaolinite. The adsorbed Al-PAM layer was able to release trapped water overtime and became more compact, while MF1011 film became more dissipative as backbones stretched out from kaolinite surface with minimal overlapping. Experimental results obtained from this study provide clear insights into the phenomenon that governs flocculation-based solid-liquid separation processes using multicomponent flocculants of anionic and cationic nature.
Adsorption kinetics of an organicÀinorganic hybrid polymer, Al(OH) 3 Àpolyacrylamide (Al-PAM), on silica and alumina were studied by a dissipative quartz crystal microbalance (QCM-D). The effects of molecular weight and aluminum content of Al-PAM on its adsorption at varying solution pH were investigated. For comparison, the adsorption of a commercial partially hydrolyzed polyacrylamide, Magnafloc1011 (MF1011), on both silica and alumina was also studied. For Al-PAM of a given molecular weight and aluminum content, the adsorption of Al-PAM on both silica and alumina was found to be highly dependent on polymer concentration and solution pH, showing stronger and more rapid adsorption on silica than on alumina within the pH range studied. Adsorption rate of Al-PAM on silica was observed to increase with increasing molecular weight and aluminum content, while Al-PAM of lower aluminum content adsorbed more favorably on alumina. Commercially available MF1011 showed negligible adsorption on silica but a stronger affinity to alumina than Al-PAM. The results of polymer adsorption determined by QCM-D correlated well with flocculation results of silica and alumina with Al-PAM and MF1011 as flocculants. Atomic force microscopic imaging revealed the morphology of polymers adsorbed on silica and alumina.
In bitumen recovery from oil sands, a percentage of the bitumen is lost to tailings. The effect of fugitive bitumen on fines settling and consolidation in tailings ponds remains controversial. In the current study, the settling performance of mature fine tailings (MFT) in response to flocculant addition was considered by studying MFT of varying bitumen content. Bitumen content in the MFT was adjusted by controlled removal of bitumen using a Denver flotation cell.
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