The facile modification of pinewood sawdust, with maleic acid, to produce a sorbent aimed at metal ion adsorption, was tested via the batch adsorption of Cd(II) ions from aqueous solution. The sorbent was characterized for the pH of zero point charge (pHZPC), spectroscopic evaluation of the surface functionalization, structural and morphological features. Factors affecting adsorption behavior, such as adsorbent dose, pH of solution, contact time and Cd(II) ion concentration were investigated. Results obtained show the adsorption rate to be comparatively fast, with equilibrium achieved after 35 min. Subsequent analysis, showed Langmuirian behavior and a monolayer adsorption capacity of 180.4 mg g -1 , at pH 6; while data derived from two-parameter and three-parameter isotherm models was evaluated using non-linear regression methods, with error analysis, to determine the most appropriate model and allow prediction of optimum parameters. The Sips isotherm model proved the most appropriate in describing the experimental data obtained in the study; with a low level of heterogeneity in the adsorption sites occupied suggesting the interaction of the metal ions
Thin‐layer solar drying experiments were conducted for the prickly pear cladode grown in Marrakech, Morocco. the experimental drying curves obtained show only a falling rate period. the results verified, with good reproducibility, that the drying air temperature is the main factor in controlling the drying rate. the expression of the drying rate equation was determined empirically from the characteristic drying curve. Eight different drying models were compared according to their correlation coefficient (r2) to estimate solar drying curves. the Page model could satisfactorily describe the solar drying curves of cladode with an r2 of 0.9995. the coefficient of this model could be explained by the effect of drying air temperature with an r2 of 1.0000.
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