Literature provides only a few examples of contamination of groundwater with microplastics, mainly investigated using a chemical approach. Little importance is given to the hydrogeological processes able to affect the contamination, such as river–groundwater interactions. This study was carried out with two aims. The first aim is the formulation of a method with a high result-to-cost ratio, based on the hydrogeological aspects of the investigated area. Microplastics were extracted from samples through filtration and successively counted and characterized morphologically through analysis of optical microscopy images. The second aim is to evaluate the presence of microplastics in some portions of an alluvial aquifer using this methodology. Microplastics in groundwater showed a higher circularity and Feret diameter than those found in surface waters, indicating that in porous aquifers the transport is likely more influenced by the microplastics’ shape than by their size. The aquifer recharge did not modify the microplastics’ characteristics in groundwater, whereas in surface water the flood wave promoted the resuspension of microplastics with lower circularity. These findings provide new pieces of evidence on the presence and transport of microplastics in both groundwater and surface waters, underlining how the hydrogeological characteristics of the area can be one of the main drivers of microplastics’ contamination.
Urban areas exercise numerous and strong pressures on water bodies, implying that different external anthropogenic factors also stress groundwater. Sewerage networks play an important role, being the place of wastewater flow. When sewerage deterioration conditions occur, aquifers can be contaminated by contaminants contained within wastewater. The study aims to verify the impact of sewerage leaks in urban semi-confined aquifers through a multidisciplinary approach. Geological, hydrogeological, hydrochemical, microbiological, and biomolecular investigations are carried out in a test site close to a sewer pipe, from February to October 2022. Microbiological analyses are carried out on a monthly basis, contextually to hydraulic head measurements in purpose-drilled piezometers. The presence of sandy intercalations and the prevalence of silt within the outcropping (about 10 m thick) aquitard makes the aquifer vulnerable to percolation from leaky sewers, therefore causing persistent microbial contamination in groundwater. The presence of fecal indicators (including pathogenic genera), corrosive and human-associated bacteria markers, is detected. The magnitude of microbiological impact varies over time, depending on hydrogeological factors such as dilution, hydrodynamic dispersion, and variation of the groundwater flow pathway at the site scale. As for personal care products, only Disodium EDTA is detected in wastewater, while in groundwater the concentrations of all the analyzed substances are lower than the instrumental detection limit.
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