The global demand for wood as a building material is steadily growing, while the availability of this natural resource is diminishing. This situation has led to the development of alternative materials. Of the various synthetic materials that have been explored and advocated, polymer composites claim a major participation as building materials. There has been a growing interest in utilizing natural fibres as reinforcement in polymer composite for making low cost construction materials in recent years. Natural fibres are prospective reinforcing materials and their use until now has been more traditional than technical. They have long served many useful purposes but the application of the material technology for the utilization of natural fibres as reinforcement in polymer matrix took place in comparatively recent years. Economic and other related factors in many developing countries where natural fibres are abundant, demand that scientists and engineers apply appropriate technology to utilize these natural fibres as effectively and economically as possible to produce good quality fibre reinforced polymer composites for housing and other needs. Among the various natural fibres, sisal is of particular interest in that its composites have high impact strength besides having moderate tensile and flexural properties compared to other lignocellulosic fibres. The present paper surveys the research work published in the field of sisal fibre reinforced polymer composites with special reference to the structure and properties of sisal fibre, processing techniques, and the physical and mechanical properties of the composites.Key words: sisal fibre, polymer, composites, structure, properties
COMPÓSITOS POLIMÉRICOS REFORÇADOS COM FIBRAS DE SISAL
RESUMOO uso da madeira como material de construção continua crescendo mundialmente enquanto a disponibilidade deste recurso natural está diminuindo. Esta situação tem conduzido ao desenvolvimento de materiais alternativos. Dentre os vários materiais sintéticos que têm sido explorados, os compósitos poliméricos reivindicam e buscam uma maior participação como material de construção. Nos últimos anos tem se observado um crescente interesse na utilização de fibras naturais como reforço de matrizes poliméricas para a produção de materiais de baixo custo. As fibras naturais são reforços com grande potencialidade e seu uso tem se dado de forma mais tradicional do que científica. Elas têm se prestado a inúmeras aplicações ao longo do tempo, mas a aplicação da tecnologia dos materiais visando a sua utilização como reforço de matrizes poliméricas é relativamente recente. As dificuldades econômicos e sociais observadas em muitos dos países em desenvolvimento, onde as fibras naturais são abundantes, requerem que cientistas e engenheiros apliquem tecnologias apropriadas para utilizar estas fibras da forma mais eficiente possível, de tal maneira que se possa produzir materiais compósitos poliméricos de boa qualidade visando a atender a demanda da população por habitações e componentes habi...
ABSTRACT:Curing of a novolac-type phenolic resin was studied by DSC. The kinetic analysis was performed by means of the dynamic Ozawa method at heating rates of 5, 10, 15, and 20°C/min. This analysis was used to determine the kinetic parameters of the curing process. The activation energy was found to be 144 kJ/mol. It was found that the Ozawa exponent values decreased with increasing reaction temperature from 3.5 to 1, suggesting a change in the reaction mechanism from microgel growth to diffusion-controlled reaction. The reaction rate constant was found to range from 123.0 to 33.6 (°C/min) n .
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