The electrolytic production of metallic zinc from processing zinc sulfide concentrates generates a residue containing cadmium, copper, and cobalt that need to be removed from the electrolytic zinc solution because they are harmful to the zinc electro-winning process. This residue is commonly sent to other parties that partly recover the contained elements. These elements can generate revenues if recovered at the zinc plant site. A series of laboratory tests were conducted to evaluate a method to process a zinc plant residue with the objective of recovering cobalt into a salable product. The proposed process comprises washing, selective leaching, purifying and precipitation of cobalt following its oxidation. The process allows the production of a cobalt rich hydroxide precipitate assaying 45 ± 4% Co, 0.8 ± 0.2% Zn, 4.4 ± 0.7% Cu, and 0.120 ± 0.004% Cd at a 61 ± 14% Co recovery. Replicating the whole process with different feed samples allowed the identification of the critical steps in the production of the cobalt product; one of these critical steps being the control of the oxidation conditions for the selective precipitation step.

No abstract

For complex orebodies in which the valuable metal is carried by several minerals that respond differently to the concentration process, an ore block model should not be characterized solely with elemental assays, as this information is not sufficient to anticipate the mill performances. Data from an iron ore concentrator is used to demonstrate the idea. A method is then proposed to estimate the mineral contents of ore samples from elemental assays. The method can readily be extended to combine the estimation of the mineral contents in the feed of the mill with an estimation of the recovery of these minerals into the products of the concentrator. These mineral recoveries can subsequently be incorporated into a block model to predict the concentrator response to the processing of an ore block.