The structural properties of CeNiGe3 have been investigated via
electron diffraction and neutron powder diffraction (NPD). This ternary
germanide crystallizes in the orthorhombic SmNiGe3-type structure
(Cmmm
space group). Electrical resistivity, ac- and dc-magnetization
measurements show that CeNiGe3 orders antiferromagnetically below
TN = 5.5(2)
K and exclude the occurrence at low temperatures of a spin-glass state
for CeNiGe3 as previously reported. Specific heat measurements
and NPD both reveal two magnetic transitions, observed at
TN1 = 5.9(2) K
and TN2 = 5.0(2)
K. Between TN1
and TN2,
the Ce magnetic moments in CeNiGe3 are ordered in a collinear
antiferromagnetic structure associated with the k1 = (100)
wavevector and showing a relationship with the magnetic
structure of the Ce3Ni2Ge7 ternary germanide. Below
TN2, this k1 = (100)
commensurate magnetic structure coexists with an incommensurate
helicoîdal magnetic structure associated with k2 = (00.409(1)1/2).
This last magnetic structure is highly preponderant below TN2 (93(5)%
in volume). At 1.5 K, the Ce atoms in CeNiGe3 carry a reduced ordered magnetic moment
(0.8(2) μB).
This value, smaller than that obtained in Ce3Ni2Ge7, results from an important
hybridization of the 4f(Ce) orbitals with those of the Ni and Ge ligands.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.