Clay mineral crystallinity and crystallite (domain) size data determined by X-ray diffraction (XRD) are methods extensively used in the characterization of very low-grade metamorphic conditions. However, the lack of sufficient interlaboratory standardization has made comparisons between different research groups unreliable due to significant variations in numerical results obtained, a consequence of the different machine conditions, measurement methods and sample preparations used during analysis. A calibration approach to the standardization of data using rock chip standards is presented, which allows data sets produced by different research groups to be directly and quantitatively compared. A standardized scale, the crystallinity index standard (CIS), is proposed, with illite crystallinity anchizonal boundary limits of 0.25"A20 and 0.4TA28, and equivalent illite crystallite sizes of 52 and 23nm, respectively, determined by the Warren-Averbach method. Calibrating both old and new data will enable more reliable comparisons between similar and contrasting geological environments, and should improve the accuracy and reliability of correlations made between XRD data and other indicators of very low-grade metamorphism, hence increasing the value of such clay mineral studies.

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Mudrock samples were investigated from two fault zones at ~3066 m and ~3296 m measured depth (MD) located outside and within the main damage zone of the San Andreas Fault Observatory at Depth (SAFOD) drillhole at Parkfi eld, California. All studied fault rocks show features typical of those reported across creep zones with variably spaced and interconnected networks of polished displacement surfaces coated by abundant polished fi lms and occasional striations. Electron microscopy and X-ray diffraction study of the surfaces reveal the occurrence of neocrystallized thin fi lm clay coatings containing illite-smectite (I-S) and chlorite-smectite (C-S) minerals. 40 Ar/ 39 Ar dating of the illitic mix-layered coatings demonstrated Miocene to Pliocene crystallization and revealed an older fault strand (8 ± 1.3 Ma) at 3066 m MD, and a probably younger fault strand (4 ± 4.9 Ma) at 3296 m MD. Today, the younger strand is the site of active creep behavior, refl ecting a possible (re)activation of these clayweakened zones. We propose that the majority of slow fault creep is controlled by the high density of thin (<100 nm thick) nanocoatings on fracture surfaces, which are suffi ciently smectite-rich and interconnected at low angles to accommodate slip with minimal breakage of stronger matrix clasts. Displacements occur by frictional slip along particle surfaces and hydrated smectitic phases, in combination with intracrystalline deformation of the clay lattice, associated with extensive mineral dissolution, mass transfer, and residual precipitation of expandable layers. The localized concentration of smectite in both I-S and C-S minerals contributes to fault weakening, with fracturing and fl uid infi ltration creating new nucleation sites for neomineralization on displacement surfaces during continued faulting. The role of newly grown, ultrathin, hydrous clay coatings contrasts with previously proposed scenarios of reworked talc and/or serpentine phases as an explanation for weak fault and creep behavior at these depths. GEOLOGICAL SETTING AND SAMPLESThe SAFOD drillhole is located along the creeping section of the San Andreas fault in central California (Fig. 1A). Northwest of the drillhole, the fault has a creep rate of 2.5-3.9 cm/yr (Titus et al., 2006); microearthquakes (Mw 0-2.0) are detected at shallow depths of 2-3 km (Nadeau et al., 2004). Drilling in summer 2005 successfully crossed the active trace of the San Andreas fault at ~3300 m MD with a measured temperature of ~112 °C

The formation of clay minerals within active fault zones, which results from the infiltration of aqueous fluids, often leads to important changes in mechanical behaviour. These hydrous phyllosilicates can (1) enhance anisotropy and reduce shear strength, (2) modify porosity and permeability, (3) store or release significant volumes of water, and (4) increase fluid pressures during shearing. The varying interplay between faulting, fluid migration, and hydrous clay mineral transformations along the central Alpine Fault of New Zealand is suggested to constitute an important weakening mechanism within the upper section of this crustal discontinuity. Well-developed zones of cataclasite and compacted clay gouge show successive stages of hydrothermal alteration, driven by the cyclic, coseismic influx of meteoric fluids into exhumed amphibolite-facies rocks that are relatively Mg rich. Three modes of deformation and alteration are recognized within the mylonite-derived clay gouge, which occurred during various stages of the fault’s exhumation history. Following initial strain-hardening and frictional melting during anhydrous cataclastic breakdown of the mylonite fabric, reaction weakening began with formation of Mg-chlorite at sub-greenschist conditions (<320 °C) and continued at lower temperatures (<120 °C) by growth of swelling clays in the matrix. The low permeability and low strength of clay-rich shears are suitable for generating high pore-fluid pressures during faulting. Despite the apparent weakening of the c. 6 km upper segment of the Alpine Fault, the upper crust beneath the Southern Alps is known to be actively releasing elastic strain, with small (<M 5) earthquakes occurring to 12 km depth. We predict that larger events will nucleate at c. 6–12 km along an anhydrous, strain-hardened portion of the fault.

A B S T R AC T : Following a round-table discussion at the Mid-European Clay Conference in Dresden 2014, new recommendations for illite 'crystallinity' Kübler index standardization have been agreed upon. The use of Crystallinity Index standards in the form of rock-fragment samples will be continued, along with the same numerical scale of measurement presented by Warr & Rice (1994). However, in order to be compatible with the original working definition of Kübler's (1967) anchizone, the upper and lower boundary limits of the Crystallinity Index Standard (CIS) scale are adjusted appropriately from 0.25°2θ and 0.42°2θ to 0.32°2θ and 0.52°2θ. This adjustment is based on an inter-laboratory correlation between the laboratories of Basel, Neuchâtel and the CIS scale. The details of this correction are presented in this first note, as discussed at the round-table meeting and will be further substantiated by a correlation program between CIS and former Kübler-Frey-Kisch standards.