In this work, we successfully demonstrated the facile fabrication of highly flexible and floatable Cu2O/rGO on Vietnamese traditional paper (VTP) for the solar-light-driven photocatalytic degradation of the antibiotic ciprofloxacin.
In this study, a new method for preparation of cross-linked magnetic chitosan particles (MCPs) from steel slag and shrimp shells using green tea extract as crosslinking reagent has been presented. The MCPs obtained were characterized by means of X-ray diffraction analysis, Fourier-transform infrared spectroscopy, scanning electron microscopy and magnetic properties, and then were used to investigate the adsorption properties of Cu(II) and Ni(II) ions in aqueous solutions. The influence of experimental conditions such as contact time, pH value, adsorbent dose and initial metal concentration, and the possibility of regeneration were studied systematically. The Cu(II) and Ni(II) adsorption isotherms, kinetics and thermodynamics have been measured and discussed. The results show that the synthesized MCPs have high adsorption capacity for both metal ions (126.58 mg/g for Cu(II) and 66.23 mg/g for Ni(II)), and have excellent regeneration stability with efficiency of greater than 83% after five cycles of the adsorption-regeneration process. The adsorption process of Ni(II) and Cu(II) on MCPs was feasible, spontaneous and exothermic, and better described by the Langmuir model and pseudo-second-order kinetic equation. The MCPs can be applied as a low cost and highly efficient adsorbent for removal of heavy metals from wastewater due to its high adsorption capacity, easy recovery and good reusability.
Hydroxyapatite and its compounds are important and promising inorganic biomaterials that can be used in dentistry and bone surgery due to its biocompatibility with the bone tissue of a living organism. The paper presents the synthesis of carbonate-substituted hydroxyapatite powders and studies their morphology, physical and chemical characteristics and biocompatibility in vivo. The synthetic carbonate-substituted hydroxyapatite are biocompatible, and they do not cause degenerative changes in the surrounding tissues. The result of this research suggests that the carbonate-substituted hydroxyapatite is promising biomaterial for orthopedic and dental prosthetics.
In this study, magnetic carboxylate-rich carbon material (Fe3O4@CRC) was synthesized via a low-temperature carbonization method and applied as an adsorbent for adsorption of Ni(II) ions and methylene blue (MB) in aqueous solution. The synthesized Fe3O4@CRC was characterized by various techniques (XRD, FTIR, FE-SEM, TEM, EDX, VSM, and BET). The adsorption kinetics, isotherms, thermodynamics, and the effects of key adsorption factors, including the pH value, initial adsorbate concentration, contact time, adsorbent dose and temperature were investigated in detail. The results showed that Fe3O4@CRC exhibited a high adsorption capacity for MB and Ni(II) with the maximum adsorption capacity of 187.26 mg/g and 106.75 mg/g, respectively. The adsorption of MB and Ni(II) on Fe3O4@CRC was a spontaneous and endothermic process, and was best described with the first-order kinetic model, Freundlich (for MB) and Langmuir (for Ni(II)) isotherm models. In addition, Fe3O4@CRC could maintain a high adsorption capacity after many consecutive cycles. Therefore, the Fe3O4@CRC material can be used as a highly efficient adsorbent for the removal of heavy metals and dyes from wastewater due to the advantages of high adsorption performance, easy separation, and good reusability.
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