Isomaltooligosaccharides (IMOs) are included in many commercially available food products including protein/fiber bars, shakes, and other dietary supplements. Marketed as "high fiber," "prebiotic soluble fiber," and/or as a "low-calorie, low glycemic sweetener," IMO may be present in significant amounts, for example, more than 15 g/item or serving. Herein, high-pressure anion exchange chromatography with pulsed amperometric detection and high-pressure liquid chromatography with differential refractive index detection are used to compare 7 commercially available IMO-containing bulk food ingredients. The ingredients are typical of those produced either (a) via bacterial fermentation ("fermented" IMO or MIMO) of sucrose in the presence of a maltose acceptor mediated by a glucosyltransferase enzyme (dextransucrase), or (b) via transglycosylation of hydrolyzed starch with α-glucosidase ("industrial" IMO). Analysis of the results with respect to digestibility suggests that the potential glycemic impact of the ingredients and products containing "industrial" IMO may be inconsistent with the product labeling and/or certificates of analysis with respect to overall fiber content, prebiotic fiber content, and glycemic response and are thus inappropriate for diabetic patients and those on low-carbohydrate (for example, ketogenic) diets.

Sweet sorghum [Sorghum bicolor (L.) Moench] is recognized as a promising biomass energy crop for meeting the increasing demand for bioenergy feedstocks. Field experiments were conducted at sites in northern and southern Louisiana for 2 yr to assess planting date and harvest maturity effects on yield from primary plantings and ratoon crops. The cultivar M81‐E was evaluated using a split plot arrangement of treatments in randomized complete block designs. Planting date from mid‐March to early July was the primary plot treatment. Harvest maturity at the early heading (EH) or hard dough (HD) stage was assigned as the subplot treatment. A range of planting dates from mid‐March to early June produced substantial yields of biomass and fermentable sugar with appropriate harvest maturity and could support sugar mill operation for up to three additional months. However, sweet sorghum planted in early May and harvested at the HD stage produced 30 to 210% more fermentable sugar than other tested planting dates and maturity combinations. Ratoon crop production was not dependable showing inconsistent tiller growth with resultant low biomass yields. Correlation coefficients of sugar yield with biomass or other quantitative agronomic characteristics were higher than 0.79, while that with brix was only 0.32 (P < 0.0001). Production management in Louisiana from long season cultivars such as M81‐E based on a single harvest 150 to 160 d from planting at the HD stage can provide more biomass and fermentable sugar than can production management targeting a ratoon crop.

BACKGROUND Aconitic acid (propene‐1, 2, 3‐ tricarboxylic acid) is the most prevalent organic acid found in sugar cane. It is used in the food processing industry as an acidulant and can be used in the synthesis of plasticizers. It can also be used to synthesize biodegradable polyesters for tissue engineering applications. In this study, aconitic acid was isolated from sugarcane molasses via liquid–liquid extraction with ethyl acetate. Six combinations of time and temperature (1–6 h at either 30 or 40°C) were tested. In order to conserve solvent, ethyl acetate was recovered and reused for subsequent extractions. The recovery of aconitic acid from vinasse was also evaluated. RESULTS Under the most efficient set of conditions, 69% of the aconitic acid was recovered as free acid. The purity (HPLC) of the extracted acid was found to be 99.9%. Ethanol was an additional stream that was generated by fermentation of molasses and yields of 12.4% (g per 100 g of molasses) were obtained. CONCLUSION The yield of aconitic acid from molasses varied from 34–69%, depending on the extraction conditions, with purity of the extracted acid being 99.9%. The aconitic acid is of a quality sufficient to synthesize polymers that could realize high‐value in biomedical applications. © 2013 Society of Chemical Industry