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The production of hydrogen to be used as an alternative renewable energy has been widely explored. Among various methods for producing hydrogen from hydrocarbons, methane decomposition is suitable for generating hydrogen with zero greenhouse gas emissions. The use of high temperatures as a result of strong carbon and hydrogen (C–H) bonds may be reduced by utilizing a suitable catalyst with appropriate catalyst support. Catalysts based on transition metals are preferable in terms of their activeness, handling, and low cost in comparison with noble metals. Further development of catalysts in methane decomposition has been investigated. In this review, the recent progress on methane decomposition in terms of catalytic materials, preparation method, the physicochemical properties of the catalysts and their performance in methane decomposition were presented. The formation of carbon as part of the reaction was also discussed.Graphic abstract

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Catalytic dry reforming of methane (DRM) is a promising way for renewable syngas production due to the utilization of both CO2 and CH4 greenhouse gases. Current approaches were made to improve the catalytic activity and coke resistance by introducing a second metal into the Ni‐based catalytic system. This bimetallic catalytic system showed a significant improvement in coke resistance due to the synergistic effect of both metals towards the reaction. This review summarizes recent developments in bimetallic catalysts in DRM which focused on the evaluation of catalysts, deactivation studies, and reaction mechanisms of developed bimetallic catalysts.