Photomechanical actuation is the conversion of light energy into mechanical energy through some smart materials. Infrared-responsive smart materials have become an emerging field of research due to easy availability and eco-friendly nature of their stimulus in the form of sunlight, which contains about 50% of near-infrared(nIR) making these materials useful at macro-scale photoactuator applications. Here, we demonstrate fabrication of highly versatile nIR triggered photoactuators based on graphene oxide/polycarbonate bilayers that offers fast, low-cost fabrication, large deflection, reversible actuation and wavelength-selective response. The photoactuators are realized by vacuum filtration of graphene oxide/water dispersion through polycarbonate membrane resulting graphene oxide/polymer bilayer structure. The photoactuation response was measured in the form of deflection from equilibrium position as a result of infrared-irradiation. The deflection is caused by the generated thermal stress at the interface of bilayers due to mismatch of thermal expansion coefficient as a results of nIR absorption by graphene oxide and subsequent temperature rise. A maximum deflection of 12 mm (circular-shaped structure with diameter 28 mm) with corresponding bending curvature of 0.33 cm−1 was shown by this photoactuator for illumination intensity of 106 mW/cm2. Few applications of these photoactuators such as sunlight-driven smart curtain, infrared actuated curtain and self-folding box are also demonstrated
We demonstrate the fabrication of highly versatile photomechanical actuators based on graphene-polymer/metal bilayers that offers fast, low-cost fabrication, large deflection, reversible actuation under zero applied pre-strain, and wavelength-selective response. The photomechanical actuator consists of a graphene nanoplatelet (GNP)-polydimethylsiloxane (PDMS) nanocomposite with a thin chromium metal coating of 35 nm thickness on the backside of the structure. The photomechanical response of the GNP-PDMS/Cr photomechanical actuator was measured by recording the variation of the bending angle upon infrared (IR) light illumination. The bending in the bilayer actuator is caused by the generation of thermal stress due to the large mismatch (the ratio being 1/20) of the thermal expansion coefficient between the two layers as a result of IR absorption by GNPs and a subsequent increase in the local temperature. The maximum bending angle was found to be about 40 degrees with a corresponding large deflection value of about 6–7 mm within 6 s for IR illumination with an intensity of 550 mW cm−2. The corresponding actuation response and relaxation times were about 1 and 3 s, respectively. The GNP-PDMS/Cr bilayer combination when integrated with the standard surface micromachining technique of micro-electromechanical system fabrication can find useful applications in the realization of micro soft-robotics, controlled drug delivery, and light-driven micro switches i.e. micro-optomechanical systems.
Graphene polymers-based soft actuators driven by infrared (IR) light have attracted wide attention recently. However, the scientific fraternity is striving hard in unraveling the area of actuators that could be triggered by IR light along with chemicals. The fabricating methodology of multiresponsive soft actuators based on graphene nanoplatelets (GNPs)-poly(dimethylsiloxane) (PDMS) nanocomposite/gold bilayers, ensuring large, fast, and reversible response, has been illustrated. The actuators display a novel dual-mode operation as photomechanical and chemomechanical actuation. The actuators are realized by depositing a thin film (100 nm) of gold on GNP-PDMS nanocomposite films resulting tubular structure on account of thermal residual stress. The actuation response of this structure upon its exposure to IR light and chemicals was measured in terms of percentage opening and degree of unscroll, respectively. The three-dimensional tubular structure is transformed into a two-dimensional sheet within 8 s under IR light irradiation. The same structures were also tested in various organic solvents like methanol, ethanol, acetone, isopropyl alcohol, and aldehydes, but the actuation has been observed only in acetone and aldehydes. This tubular actuator unscrolls completely and then scrolls in opposite direction along with tube axis shift through 90° during its exposure to acetone (liquid/vapors) and aldehydes. Few applications of these actuators, such as multimode soft grippers for on-demand capture/release of objects (with weight 1.2 times the actuator's own weight) and volatile organic compounds detection module, have been demonstrated. The combination of surface micromachining techniques of microelectromechanical systems process with this smart material may find applications in drug-delivery systems with precise control, soft robotics, and noninvasive diagnosis of diabetes and breast/lung cancers.
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