Aspirin resistance and relatively compromised venous endothelial cell integrity together marked patients whose vein grafts failed within days after off-pump coronary artery bypass grafting. These observations form a basis for identifying patients at risk and developing approaches to prevent vein injury or to selectively intervene in high-risk circumstances.

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Purpose -This paper seeks to present a prognostics approach using the Mahalanobis distance (MD) method to predict the reliability of multilayer ceramic capacitors (MLCCs) in temperature-humidity-bias (THB) conditions. Design/methodology/approach -Data collected during THB testing of 96 MLCCs were analyzed using the MD method. In the THB tests, three parameters (capacitance (C), dissipation factor (DF), and insulation resistance (IR)) were monitored in situ. A Mahalanobis space (MS) was formed from the MD values of a set of non-failed MLCCs. MD values for the remaining MLCCs were compared with an MD threshold. Data for MLCCs which exceeded the threshold were examined using the failure criteria for the individual electrical parameters to identify failures and precursors to failure. Findings -It was found that the MD method provided an ability to detect failures of the capacitors and identify precursors to failure, although the detection rate was not perfect. Research limitations/implications -It was observed that the quality and construction of the MS, together with the choice of the MD threshold, were the critical factors determining the sensitivity of the MD method. Recommendations are offered for improved sensitivity to enable assessment of intermittent failures. Originality/value -MD analysis of the multivariate MLCC data set illustrates how detection of failures can be simplified in a system for which several parameters were monitored simultaneously. This makes the MD method of great potential value in a health-monitoring system.

A liquid crystalline thermoset (LCT), 4,4′‐diglycidyloxy‐α‐methylstilbene/sulfanilamide, is studied by dynamic mechanical and vapor sorption measurements. Sub‐Tg transitions are assigned to the specific segmental motions through molecular modeling and used to define the environmental temperatures for the study of water transport properties in LCT. The variation of moisture transport with amine‐epoxy ratio reveals that the crosslink density and local concentration of polar groups play the key role in determining both the diffusivity and solubility. The LCT exhibits much lower water diffusion than analogous isotropic networks while the solubility is essentially the same. Segmental flexibility and an ordered smectic layered structure are responsible for the lower permeability.