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Viscosity and crystallization are essential properties to characterize the lubrication and heat transfer performances of mold flux. Therefore, in this paper, the viscosity and crystallization behaviors of conventional F-containing commercial mold flux and newly designed F-free mold fluxes were investigated by using rotating cylinder method and Single/Double Hot Thermocouple Technique (SHTT/DHTT). Results shows that the viscosities of designed F-free mold fluxes are close to the F-containing mold flux; and the crystallization temperatures of F-free mold fluxes increases with the increase of basicity and Na 2 O/Li 2 O content; while it decreases with the increase of cooling rate and the addition of B 2 O 3 . The final steady state structure of F-free mold fluxes during the DHTT tests shows it is composed of a major crystalline and a thin liquid layer (5.42-7.2%) without glass phase. The results of XRD indicate that the main crystalline phases formed in designed F-free mold fluxes were calcium borosilicate (Ca 11

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As potential substitutes for fluorides, the influences of basicity and B2O3 content on viscosity, melting and crystallization behaviors of low fluorine mold fluxes for casting medium carbon steels were investigated by using Brookfield viscometer and Single Hot Thermocouple Technique in this study. Results suggested that, the break temperature, crystallization temperature and critical cooling rate of low fluorine mold fluxes were increased with the increase of basicity; while they were decreased with the further addition of B2O3. Meantime, the viscosity and melting temperature range were first attenuated, and then increased greatly with the increase of basicity; however, they would tend to be reduced with the addition of B2O3 content. Also, it was found that the viscosity of mold flux is not only decided by the degree of polymerization of silicate structure, but also greatly affected by its crystallization behavior.