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NH3, and cyclohexylimine, since only the imine can be readily explained by radical attack on the parent amine.2C6HnNH2 + 2HN -> C6HuNHNH2 + CeH10NH + NH3 The difference in chemical behavior between the two azide salts may be ascribed to the difference in structure and ease of diffusion through the crystal lattice of the two initially formed radicals, amino and cyclohexylamino, and the corresponding bases. The large and structurally complex cyclohexylamino radical results in stable products, such as imine and cyclohexyl-substituted hydrazines, while surfacing. Heterogeneous reaction depends upon the ability of survival or regeneration of reactive species, like the amino radical, within the solid azide such that they can finally diffuse to the surface and react. Figure 2. Log /tobad vs.

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