The sequential combination of ultrasonication and ozonation as sewage sludge treatment prior to anaerobic digestion was investigated. Synergistic volatile suspended solids (VSS) solubilization was observed when low energy ultrasonication (⩽12kJg(-1) TS) was followed by ozonation. 0.048gO3g(-1) TS ozonation induced the maximum VSS solubilization of 41.3% when the sludge was pre-ultrasonicated at 9kJg(-1) TS; while, the same ozone dosage applied without prior ultrasonication only induced 21.1% VSS solubilization. High molecular weight (MW) components (MW>500kDa) were found to be the main solubilization products when sludge was only ozonated. However, solubilization products by ozone were mainly in the form of low MW components (MW<27kDa) when sludge was pre-ultrasonicated. The high MW products generated by ultrasound were effectively degraded in the subsequent ozonation. Anaerobic biodegradability increased by 34.7% when ultrasonication (9kJg(-1) TS) and ozonation (0.036gO3g(-1) TS) were combined sequentially. The maximum methane production rate increased from 3.53 to 4.32, 4.21 and 4.54mL CH4d(-1) after ultrasonication, ozonation and ultrasonication-ozonation pre-treatments, respectively.

This work provides insights on the solubilization products after a simultaneous combination of alkaline and ultrasonic (ALK+ULS) pre-treatment of sewage sludge. Soluble chemical oxygen demand (SCOD) increased from 1200 to 11,000 mg/L after such treatment. Organics with molecular weight around 5.6 kDa were solubilized because of the synergistic effect of ultrasound and alkali. Organics with molecular weight larger than 300 kDa increased from 7.8% to 60%, 16% and 42.3% after ULS, ALK and ALK+ULS treatment, respectively. Excitation emission matrix fluorescence spectroscopy analysis identified soluble microbial product-like and humic acid-like matters as the main solubilization products. Sludge anaerobic biodegradability was significantly enhanced with the simultaneous application of ALK+ULS pre-treatment. ALK+ULS pre-treatment resulted in 37.8% biodegradability increase compared to the untreated sludge. This value was higher compared to the biodegradability increase induced by individual ALK pre-treatment (5.7%) or individual ULS pre-treatment (20.7%) under the same conditions applied.

Highlights  Median diameter of bioflocs dropped from 45.3 to 15.9 μm after ULS treatment  SCOD increased from 200 to 2,648 mg/L after ULS+ALK post-treatment  SMP and HA-like substances were produced as a result of combined posttreatments  Methane production increased by 48.3% after ULS-Ozone post-treatment.  Ozone and ALK induced synergistic effects when combined with ULS treatment.

Experience with compressor valve modelling has shown that reciprocating compressor performance can sometimes be improved by subtle changes in valve design. Modelling has led to a better understanding of the physical behaviour of valves and of the compression process. Three compressor valve studies presented here demonstrate the benefits of valve modelling. Case 1 challenges the commonly held assumption that reducing the lift of a compressor valve will reduce the efficiency of the compressor. The capacity of this compressor is increased by reducing the valve lift. A plot of BHP/MMSCFD versus valve lift shows an inflection point that assists the analyst in optimizing the design. Case 1 also presents a method of calculating the economic effect of improvements in valve performance. Case 2 demonstrates the effect of inadequate flow area through the valve. Pressure in the clearance volume cannot decrease fast enough if flow areas are inadequate; the result is late valve closure, and therefore decreased valve life. Case 3 shows the importance of considering the design of the cylinder casting in addition to that of the valves. Here, insufficient cylinder flow area constricted gas flow. Since these cases were simulated, the analyst had the opportunity to evaluate the proposed solution over the entire range of operating conditions. He was able to select a valve which solved the immediate problem and be confident that it would perform adequately throughout the specified range of conditions.

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