Understanding the chemo-mechanical mechanisms that direct the motion of self-propulsive colloids is important for the development of active materials and exploration of dynamic, collective phenomena. Here, we demonstrate that the...

Stabilization of oil–oil interfaces is important for nonaqueous emulsions as well as for multiphase oil-in-water emulsions, with relevance to a variety of fields ranging from emulsion polymerization to sensors and optics. Here, we focus on examining the ability of functionalized silica particles to stabilize interfaces between fluorinated oils and other immiscible oils (such as hydrocarbons and silicones) in nonaqueous emulsions and also on the particles’ ability to affect the morphology and reconfigurability of complex, biphasic oil-in-water emulsions. We compare the effectiveness of fluorophilic, lipophilic, and bifunctional fluorophilic-lipophilic coated nanoparticles to stabilize these oil–oil interfaces. Sequential bulk emulsification steps by vortex mixing, or emulsification by microfluidics, can be used to create complex droplets in which particles stabilize the oil–oil interfaces and surfactants stabilize the oil–water interfaces. We examine the influence of particles adsorbed at the internal oil–oil interface in complex droplets to hinder the reconfiguration of these complex emulsions upon addition of aqueous surfactants, creating “metastable” droplets that resist changes in morphology. Such metastable droplets can be triggered to reconfigure when heated above their upper critical solution temperature. Thus, not only do these bifunctional silica particles enable the stabilization of a broad array of oil-fluorocarbon nonaqueous emulsions, but the ability to address the oil–oil interface within complex O/O/W droplets expands the diversity of oil chemical choices available and the accessibility of droplet morphologies and sensitivity.

We have demonstrated that adsorption of silica nanoparticles at the interface of a solubilizing oil droplet in surfactant solution can significantly accelerate the droplets’ self-propulsion speed. Using fluorescent particle visualization, we correlated the degree of particle surface coverage on bromodecane droplets to the droplet speed in TX surfactant. Slowest speeds were found at the lowest and highest surface coverages and the fastest speeds were achieved at intermediate surface coverages of about 40%. The particle-assisted propulsion acceleration was further demonstrated in nonionic, anionic, and cationic surfactants and a range of oils with varying solubilization rates. We propose that particles at the droplet interface hinder solubilization by displacing oil-water interfacial area, providing asymmetry in the distribution of oil-filled micelles along the droplet surface and accelerating Marangoni flow. We describe a fluid-mechanical model to rationalize the effect of the particles by considering the effect of a non-symmetrical distribution of solubilized oil at the droplet surface. Approaches by which to modulate the distribution of solubilization across droplet interfaces may provide a facile route to tuning active colloid speeds and dynamics. <br>