The main discoveries and advances in the development of industrial processes for the most commercially used phosphate fertilizers in the world (single superphosphate, triple superphosphate, monoammonium phosphate, and diammonium phosphate) occurred from 1830 to 1970, followed by improvements and investments to expand worldwide production capacity. A main opportunity now is aggregating new technologies to conventional phosphate fertilizers so they may become even more efficient in supplying P to plants, which involves research related to the technologies for reduction in soil P losses. Thus, some innovations and technologies have begun to be developed and marketed and continue in continual refinement and adoption in agriculture worldwide to reduce conversion of soluble P applied through conventional phosphate fertilizers into unavailable forms in the soil. This is the case of enhanced efficiency fertilizers, which includes groups of phosphate fertilizers with fixation inhibitors and the chemically modified, controlled-release, blends, multifunctional, and synergistic phosphate fertilizers. The technologies presented in detail in this paper were developed to improve the agronomic efficiency of phosphate fertilization in comparison with conventional fertilizers, with costs varying according to raw materials, production technologies, and distance from the consumer market. This synthesis expands knowledge regarding technologies in use, stimulating the development and application of technologies that increase nutrient efficiency, based on results obtained through suitable methods and equipment along with laboratory, greenhouse, and field results. Increased fertilization efficiency should always be linked with greater economic profitability and the lowest environmental impact, following the principles of sustainability and circular economy. The great challenge for innovation is transforming the knowledge generated regarding fertilizers present in patents and scientific publications into technologies appropriate for the fertilizer market and for adoption in agriculture.

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The objective of this study was to evaluate nutrient consumption and exports in agricultural systems of Latin America and the Caribbean (ALC) in order to estimate the balance of the main macronutrients (N, P and K) used by crops. The nutrient balance was estimated by considering the amount of nutrients entering the agricultural systems via fertilization and biological N2 f ixation (BNF) and the amount of nutrients leaving the systems through crop harvest removal in each country. Based on off icial statistics for the year 2016, the ALC region presented a positive balance of nitrogen. However, some countries (Argentina, Bolivia and Paraguay) had a negative balance of N. Biological N2 f ixation is the main source of N in Latin American agriculture, accounting for more than 62% (11.29 Mt N) of the total N (18.10 Mt N) entering the agricultural systems. Broadly speaking, the supply of P via fertilizer in Latin America counterbalanced the removal through crop harvest, with the exception of Argentina, Bolivia, Guatemala and México, which have crop production dependent on soil P mining. Potassium was one of the nutrients whose application does not meet the demand of the region’s crops, presenting negative balances in almost all countries except Brazil, Colombia and Venezuela. Nevertheless, it should be noted that many agricultural soils from this region have naturally high K availability. Greater care in the use of inputs, including fertilizers, occurs with cropping soybean, corn, coffee, sugarcane and oranges, while the rest are dependent on natural soil fertility, which may compromise food safety.

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