Laser metal deposition (LMD) is utilized to clad the surface of a miniaturized test roll (Ø 40 mm) of tool steel. The cladding consists of two layers: a nickel alloy as intermediate layer deposited onto the surface of the steel substrate, and a metal matrix composite (MMC) as top layer consisting of spherical tungsten carbide particles embedded into the nickel alloy matrix. The thermomechanical wear behavior of the cladding is investigated on a test rig, where the test roll is pressed against an inductively heated load roll. Multiple test runs up to several hours simulating industrial loading conditions are performed. The presented testing procedure enables predicting the time-dependent abrasive wear behavior of the cladding, in particular for hot rolling mill applications. After testing for 8 h at temperature of 650 C and at contact pressure of approximately 1 GPa, the maximum depth of the wear mark is about 0.12 mm. Partial cracking, debonding and dissolution of the tungsten carbide particles, as well as formation of iron and chromium oxides at the surface of the wear marks occur. However, as low abrasive wear is observed, the investigated MMC may potentially be applicable for cladding rolls in steel hot rolling mills.
The thermodynamic modeling of alloy systems consisting of stable and metastable phases e.g. high-alloyed mottled cast iron can be problematic. Thermodynamic databases are rather well-developed for low, medium and high alloyed steels (e.g. HSS) but the application of those databases is not yet very common for high-alloyed (mottled) cast irons.
The Thermo-Calc software together with the TCFE7 database is used to calculate isopleth and property diagrams, using the CALPHAD method. Additionally Scheil-Gulliver calculations are performed to simulate the effects of microsegregation during solidification. The results from the thermodynamic calculations are compared with measurements on own samples and with literature values. Those measurements include quantitative light-optical analysis, SEM with BSE detector, EDX measurements for the distribution of the alloying elements as well as XRD and DSC measurements.
The investigations show the possibilities which are offered by thermodynamic calculations for high-alloyed mottled cast iron as well as the limitations and the compromises which have to be taken into account when calculating stable and metastable phases existing next to each other.
The cover shows the microstructure of a metal matrix composite consisting of tungsten carbide particles embedded in a nickel alloy matrix. The diameter of the spherical particle at the center is about 40 μm. The EDX maps illustrate different contents of tungsten (orange) and nickel (yellow) inside the particles and inside the matrix, respectively. Further information can be found in the article by Josef Domitner and co‐workers, article number http://doi.wiley.com/10.1002/srin.201900478.
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