In this work, a novel single-stage process for in situ synthesis of Ag nanoparticles (NPs) using the layer-bylayer (LbL) technique is presented. The Ag NPs were formed into nanotextured coatings based on sequentially adsorbed poly(allylamine hydrochloride) (PAH) and SiO 2 NPs. Such highly porous surfaces have been used in the fabrication of highly efficient ion release films for applications such as antibacterial coatings. In this approach, the amino groups of the PAH acted as reducing agent and made possible the in situ formation of the Ag NPs. This reduction reaction occurred during the LbL process as the coating was assembled, without any further step after the fabrication and stabilization of the multilayer film. Biamminesilver nitrate was used as the Ag + ion source during the LbL process and it was successfully reduced to Ag NPs. All coatings were tested with gram-positive and gram-negative bacterial cultures of Escherichia coli, Staphylococcus aureus, and Lactobacillus delbrueckii showing an excellent antimicrobial behavior against these types of bacteria (more than 99.9% of killing efficiency in all cases).

In this work we propose a novel antibacterial coating composed of SiO2 and the polymer Poly(allylamine hydrochloride) (PAH). The coating was fabricated by the technique Layer‐by‐Layer (LbL). This technique has already been used in previous works, and it has the advantage that it allows to control the construction of nanosized and well organized multilayer films. Here, the new nanotexturized LbL SiO2 surface acts as antibacterial agent. The fabricated coatings have been tested in bacterial cultures of genus Lactobacillus to observe their antibacterial properties. It has been demonstrated these PAH/SiO2 coating films have a very good antimicrobial behaviour against this type of bacteria. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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