The bonding state between the carbon fiber and the polymer directly affects the properties of carbon fiber reinforced polymer composites (CFRP), which is influenced by the surface structural characteristics of carbon fiber (CF). The surface of CF is composed of tightly packed graphite crystallites lacking active carbon atoms, which results in low surface energy of CF and weak interfacial performance of CFRP. The interfacial properties can be evaluated indirectly through macro-mechanical properties, and can also be characterized by micromechanical testing methods. In order to improve the interfacial combination between the carbon fiber and the polymer, it is usually to modify the interface of CFRP, which mainly includes carbon fiber surface functionalization, carbon fiber surface coating and introduction of micro-nano enhancement phase. In this paper, researches on the interfacial properties of CFRP were reviewed, and the existing problems and the future research focus were also discussed.
Atomic or molecular simulation technology is gradually used in the performance simulation of organic ballistic fibers and their composites, to reveal their various performance mechanisms and evolutionary mechanisms from the molecular point of view. Atomic or molecular simulation technology in the mechanical properties, thermal properties, aging properties, properties of aramid fiber composite fibers, and interface properties of aramid fiber-reinforced composites are summarized in this paper.
A study on the microscopic morphology of real-world polymer blends and its mechanism of change showed that the microscopic morphology of equiproportional mixtures gradually changed from a dense body structure to a network structure with the addition of the total polymer concentration up to 20%; the microscopic morphology of mixtures with different proportions was characterized by the most uniform network structure of equiproportional mixtures when the total polymer concentration was 20%. The polymer acts as a defoamer in the mixed system. In this paper, the relationship between the microscopic morphology of each mixture and the physicochemical behavior of the two polymer chains in the mixed system was investigated on the basis of the Aifantis strain gradient theory. Molecular polymer microscopic interface and multiscale failure analysis are proposed. It is shown that for the dihedral angle distribution of four consecutive coarse-grained particles, the peaks obtained from all atomic-scale simulation data are reproduced in the coarse-grained model simulations. The deviation is within 2.5% in most places, except for the local area where the deviation exceeds 5%. Therefore, we have achieved good results for large-scale failures.
Carbon fiber reinforced epoxy composites is playing a role in reducing structural weight and costs, saving resources and optimizing processes. However, the low properties of epoxy matrix and the weak interfacial bonding between carbon fiber and epoxy lead to the poor interlaminar performancec for carbon fiber or fabric reinforced epoxy composites. The application of nanomaterials is an effective way to improve or enhance the interlaminar properties of composite materials. Therefore, this paper summarized the research on the methods of nanomaterialsto reinforce resin matrix, and nanomaterials-carbon fibers multi-scale reinforcement to enhance the interlaminar performace, and nanomaterials to distribute the surface of prepreg uniformly, and nanomaterials to promote interfacial binding energy between carbon fiber and epoxy and nanomaterials macrostructure to improve the interlaminar properties of composites.
Application and key manufacturing technologies of new types of fiber reinforced composites in safety ranges were reviewed in this paper. To make full use of high-property kinds of fibers and develop more better-property fiber reinforced composites, the corresponding goodness and weakness and manufacturing key technologies are given so as to find appropriate and innovative new-technological cases and provide suggestions support for deeper researches.
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