Low safety, unstable interfaces, and high reactivity of liquid electrolytes greatly hinder the development of lithium metal batteries (LMBs). Quasi‐solid‐state electrolytes (QGPEs) with superior mechanical properties and high compatibility can meet the demands of LMBs. Herein, a biodegradable polyacrylonitrile/polylactic acid‐block‐ethylene glycol polymer (PALE) as membrane skeleton for GPEs is designed and systematically investigated by regulating the length and structure of the cross‐linked chain. Benefiting from the enriched affinitive sites of polar functional groups (CO, COC, CN, and OH) in highly cross‐linked polymer structure, the designed PALE membrane skeleton exhibits flame‐retardant property and ultrahigh liquid electrolyte uptake property, and the derived quasi‐solid‐state PALE GPEs deliver enhanced stretchability and a higher electrochemical stable window of 5.11 V. Besides, the PALE GPEs effectively protect cathodes from corrosion while allowing uniform and fast transfer of Li+ ions. Therefore, the Li||Li symmetrical battery and LFP or NCM811||Li full‐cell using PALE GPEs exhibit excellent cycling stability coupled with compact and flat inorganic/organic interface layers. And the excellent cycling stability of pouch cells under harsh operating conditions indicates the application possibilities of PALE GPEs in flexible devices with high‐energy‐density.
Triblock Polymer Electrolyte
In article number 2300425, Anqiang Pan, Zhi Chang, and co‐workers construct a triblock polyacrylonitrile/polylactic acid‐block‐ethylene glycol polymer as skeleton for gel electrolyte, in which the triblock chain structure and increased electronegative functional groups in extended polymer chains play important roles in directing the transport of Li+ ions and forming compact interface layers.
Labyrinth seals on both rotor casing and blade tip as an effective method to control the leakage flowrate of the shroud and improve aerodynamic performances in a transonic turbine stage are investigated in this study. Compared to the case without the labyrinth seal structure, the cases with three different types of sealing teeth have been shown to reduce significantly the tip leakage flow by computational simulations. The double-side sealing teeth case reduces the leakage flowrate mleakage/mpassage from 3.4% to 1.3% and increases the efficiency by 1.4%, which is the maximum efficiency improvement of all cases. The sealing structures increase the loss inside the shroud while reducing the momentum mixing between shroud leakage flow and mainstream. Therefore, the circumferential distribution of leakage velocity is changed, as well as the distribution of high-loss zones at turbine outlet. Furthermore, the leakage-vortex loss, which is associated with the blockage effect of sealing structure to the tip leakage flow, gains more improvement than the passage-vortex at the rotor outlet section in double-side seal case. In addition, it has also been found that with a larger gap at tip, the double-side seal has better effects of reducing the leakage flow and improving the aerodynamic performance in the transonic turbine stage.
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