Abstract. The paste pH test (1 part solid: 2 parts water) is one method used to determine the acidic nature of a rock/soil sample. In conjunction with kinetic NAG testing a classification scheme has been developed for the Cypress Prospect within the Stockton coal mining region, West Coast, New Zealand. Samples having a paste pH of < 4.0 are considered potentially acid forming (PAF) and contain significant acidic sulfate salts (up to 30.1 kg H 2 SO 4 /t equivalent) that will immediately produce acid upon exposure to water. Samples with a paste pH of 4.0 -5.0 are considered PAF, but have a lower stored acidic salt content (up to 9.0 kg H 2 SO 4 /t equivalent). In the field the lithologies represented by both these rock types are likely to generate ARD immediately upon exposure to water. Circum-neutral paste pH values (> pH 5.0) for samples classified PAF indicated that they have a short-term acid neutralization capacity (ANC) that is greater than the readily available short-term acid generating capacity of the sample. This resulted in a time lag (2 -356 minutes) prior to decrease to pH 4 in the kinetic NAG test. Samples having a paste pH > 6.0 typically produced a longer lag period than those with a paste pH of 5 -6. As previous researchers have demonstrated this represents a lag period prior to the onset of laboratory acid rock drainage in larger column leach tests. These results have direct application to strategic mine planning at the proposed Cypress mine including separating waste rock into immediate acid generators (high management priority) from acid generators with a lag to acid formation (lower priority) and non-acid forming. Field validation of this classification system is still needed.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2025 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.