The redox-activity of Cl−-hosting polypyrene cathode in dual-ion batteries can be tuned by tailoring the linking patterns.

Recent studies have demonstrated that dihydrophenazine (Pz) with high redox-reversibility and high theoretical capacity is an attractive building block to construct p-type polymer cathodes for dual-ion batteries. However, most reported Pz-based polymer cathodes to date still suffer from low redox activity, slow kinetics, and short cycling life. Herein, a donor-acceptor (D-A) Pz-based conjugated microporous polymer (TzPz) cathode is constructed by integrating the electron-donating Pz unit and the electron-withdrawing 2,4,6-triphenyl-1,3,5-triazine (Tz) unit into a polymer chain. The D-A type structure enhances the polymer conjugation degree and decreases the band gap of TzPz, facilitating electron transportation along the polymer skeletons. Therefore the TzPz cathode for dual-ion battery shows a high reversible capacity of 192 mAh g −1 at 0.2 A g −1 with excellent rate performance (108 mAh g −1 at 30 A g −1 ), which is much higher than that of its counterpart polymer BzPz produced from 1,3,5-triphenylbenzene (Bz) and Pz (148 and 44 mAh g −1 at 0.2 and 10 A g −1 , respectively). More importantly, the TzPz cathode also shows a long and stable cyclability of more than 10 000 cycles. These results demonstrate that the D-A structural design is an efficient strategy for developing high-performance polymer cathodes for dual-ion batteries.

Photocatalytic hydrogen production based on dibenzothiophene-S,S-dioxide (BTDO)-containing polymer photocatalysts have attracted much attention in recent years, due to the high hydrophilicity and strong electron withdrawing capability of BTDO. However, most...