High-performance metal-organic framework (MOF)/polyimide (PI) mixed matrix membranes (MMMs) are fabricated by a facile strategy by designing the MOF/PI matrix interface via poly dopamine coating. The overall separation performance of the designed MMMs surpasses the state-of-the-art 2008 Robeson upper bound for the H2 /CH4 and H2 /N2 gas pairs and approaches the 2008 upper bound for the O2 /N2 gas pair.
Oil-contaminated wastewater threatens our environment and health, especially that stabilized by surfactants. Conventional separation protocols become invalid for those surfactant-stabilized nanoemulsions due to their nanometer-sized droplets and extremely high stability. In this paper, photothermal-responsive ultrathin Au nanorods/poly(N-isopropylacrylamide-co-acrylamide) cohybrid single-walled carbon nanotube (SWCNT) nanoporous membranes are constructed. Such membranes are capable of separating oil-in-water nanoemulsions with a maximum flux up to 35 890 m(2)·h(-1)·bar(-1) because they feature hydrophilicity, underwater oleophobicity, and nanometer pore sizes. It is remarkable that the permeation flux can be simply modulated by light illumination during the process of separation, due to the incorporation of thermal-responsive copolymers and Au nanorods. Meanwhile, it shows ultrahigh separation efficiency (>99.99%) and desired antifouling and recyclability properties. We anticipate that our ultrathin photothermal-responsive SWCNT-based membranes provide potential for the generation of point-of-use water treatment devices.
Single-layered MoS2-based ultrathin membranes with well-controlled thicknesses are prepared by a simple filtration method, and for the first time applied to gas separation. These membranes exhibit superior H2/CO2 separation performance and extremely high H2 permeance. The H2/CO2 separation performance surpasses the state-of-the-art upper-bound of polymeric and inorganic membranes.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.