The present study reports on rheological properties of rejuvenated non-aged and aged bitumen samples with a pyrolytic product (PP) as a rejuvenator. Various experimental and numerical methods were used in order to investigate the addition of various concentrations of PP to aged and non-aged bitumen samples. It was confirmed that the application of PP as a rejuvenator to the aged bitumen has been successful. The main focus of the study was on the use of several mathematical and mechanical models, which would successfully describe and predict experimental results. Precise calculations for the complex modulus were obtained by generalised five-parameter Sigmoidal model, while the Al-Qadi model enabled good predictions for the phase angle estimations. However, better predictions of rheological parameters were obtained for non-aged bitumen. The results confirmed the possibility of using the prediction models for the estimation of various rheological properties of aged and non-aged bitumen samples with the addition of rejuvenator.
For many years the properties of bitumen have been determined based on mechanical tests as needle penetration, Ring&Ball and Fraass fracture temperature. For elastomer (styrene-butadiene-styrene) polymer modified bitumens these tests are not sufficient to show the important differences in bitumens. Elastic recovery and cohesion provide better insight, but rheological properties cannot be adequately described with conventional test. The requirements of the polymer modified bitumens (PmB) in Europe were defined in EN 14023 in 2010 [1]. Since then several new tests were introduced in the research field and their procedures improved. In the European Standards Committee (CEN) TC 336, there is ongoing work to develop performance related specifications. New laboratory test methods from American standards were adapted and transformed into EN standards (bitumen laboratory aging methods and rheological tests). These test methods are not yet employed in the current PmB European standard, however, the draft prEN 14023, April 2020 [2] suggests these new tests. In the recent years at ZAG Laboratory for asphalts and bitumen-based products long-term aging of bitumen by pressure aging vessel (PAV) and rheological tests were introduced. Traditional bitumen test methods are performed together with new rheological tests e.g. Dynamic Shear Rheometer (DSR) testing, to characterize complex modulus and phase angle, and Multiple Stress Creep Recovery Test (MSCRT) in order to develop a preliminary data base on PmB’s, which are frequently used in Slovenia. The paper presents the current requirements for PmB’s in Slovenia and test results on PmB 45/80-65, original, laboratory aged and extracted from produced asphalt mixtures.
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