It is difficult to obtain γ-Fe2O3 nanostructures by heating iron substrate in ambient conditions because γ-Fe2O3 is less thermodynamically stable than α-Fe2O3. In this work, we synthesize γ-Fe2O3 nanowires by heating iron particles under an external force. The stacking style of iron and oxygen ions under a strong shearing stress tends to adopt the γ-Fe2O3 structure regardless of the thermodynamic restriction. These γ-Fe2O3 nanowires exhibit a clear ferromagnetic property. Transmission electron microscopy (TEM) and X-ray diffraction (XRD) measurements confirm that γ-phase structure appears only under the applied external force during the heating period. A window of the magnitude of the external force is found to help the nanowire growth on iron particles. The growth mechanism of γ-Fe2O3 nanowires other than α-Fe2O3 under the external force is discussed and an applied stress-assisted growth model is proposed. This work presents an easy approach to produce ferromagnetic iron oxide nanowires on a large scale.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
customersupport@researchsolutions.com
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.
Copyright © 2025 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.