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In 2011, with the successful isolation of Ti3C2, a door of 2D layered MXene has been opened and received growing attention from researchers. MXene refers to a family of two-dimensional (2D) materials made up of atomic layers of the transition metal, carbide, nitrides, or carbonitrides. Given the large surface area, adjustable surface terminal groups, and excellent conductivity of MXene, it has shown exciting potential in photocatalysis, energy conversion, and many other fields. Among many 2D MXene, Ti3C2 was the most studied for its availability, low cost, facile modification procedure, and outstanding electronic properties. In previous investigations, Ti3C2 has shown huge potential in the photocatalysis area. Ti3C2 in a photocatalysis system can enhance the separation of photoinduced electrons and holes, reduce charge recombination, and thus improve the photocatalysis performance in many systems. To adjust the performance of Ti3C2 in different applications, the properties of Ti3C2 including morphology, structures, and stability are tunable by different post-processing method in the hybridized materials. In this review, an all-around understanding of the fabrication and modification methods of Ti3C2 and their connection to photocatalytic applications of Ti3C2 MXene based materials are presented. Moreover, a summary and our perspectives of Ti3C2 are given for further investigation.

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In recent years, photocatalytic technology has been widely studied as an environmental restoration technology and energy production technology to solve the two crises of energy shortage and environmental pollution.