Groundwater in the north-eastern suburb of Tallinn was analysed to determine the content of iron, manganese, sulphides, ammonia, and radionuclides (Ra 226 , Ra 228 ) and total radioactivity. It was established that for several wells of the Cambrian-Vendian water layer the annual effective dose would exceed the EU guideline for drinking water (0.1 mSv/yr). The purpose was to find a technology for simultaneous purification of groundwater from iron, manganese, sulphides, ammonia, and some radionuclides (Ra 226 , Ra 228 ). A pilot plant consisting of a Venturi-type aeration unit GDT (Gas-Degas Technology, Mazzei Corp., USA), an oxidation tank, and two-stage filtration columns was constructed. Several non-catalytic (Everzit Special Plus, sand) and catalytic filter materials (Filtersorb FMH, Pyrolox) were tested. Along the flow sheet from the aerator to the II stage filter outlet the pH, dissolved oxygen and carbon dioxide, turbidity, the content of iron, manganese, and ammonia were monitored, mainly by using spectrophotometry (HACH DR/2000). Radioactivity of water samples was determined by the Estonian Radiation Centre using the liquid scintillation counting method and γ-spectrometry. It was established that by intensive aeration of groundwater followed by oxidation for a certain contact time and appropriate selection of filter materials of different properties, it was possible to remove together with iron and manganese also radium isotopes. The total effectiveness of the process was 90% removal of gross-alfa and 70% removal of gross-beta activity of groundwater. Since the uranium content in the well water was marginal and radon was almost totally (99%) removed in the degas separator, the total effective dose was calculated by Ra 226 and Ra 228 . It was about 0.067 mSv/yr, which is lower than the EU DWD guideline (0.1 mSv/yr). The theoretical assumption that radionuclides were already removed with Fe(OH) 3 flocks in the first filtration step was verified by examining wash water. The radioactivity of wash water containing precipitate and the filtered wash water were measured. Results showed 4.6 times higher gross-alfa and 5.3 times higher gross-beta activity in the water containing precipitate. The co-precipitation process, where MnO 2 and Fe(OH) 3 flocks played an essential role, resulted in simultaneous removal of radium isotopes. Co-precipitation of radium with MnO 2 was more effective than with Fe(OH) 3 .

The purpose of this work has been to elaborate a cost-effective and relatively simple technology for groundwater simultaneous purification from iron, manganese, sulfides, ammonia, and some radionuclides (Rn 222 , Ra 226 , Ra 228 ). A pilot plant consisting of the Venturi-type aeration unit GDT (Gas-Degas Technology, Mazzei Corp. USA), an oxidation tank and two-stage filtration columns was constructed. Different non-catalytic (Everzit Special Plus, sand etc.) and catalytic filter materials (Filtrasorb FMH, Pyrolox etc.) as well as zeolites were tested. It was found that intensive aeration of groundwater, followed by oxidation with certain contact time, and appropriate selection of filter materials of different properties, enable removal of radium isotopes together with iron and manganese. Total effectiveness of the process was 90% removal of gross-alfa and 70-75% removal of gross-beta activity of groundwater. The total average effective dose was calculated by residual Ra 226 and Ra 228, and was about 0.07 mSv/yr, which meets the EU DWD requirement (0.1 mSv/yr). On the basis of the results of the pilot plant studies, a full scale plant (2500 m 3 /d) of Viimsi Water Ltd. was designed by the SWECO Project. The plant will be put into operation in January 2012.

No abstract

No abstract